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Effect of pore generator on microstructure and resistivity of Sb2O3 and CuO doped SnO2 electrodes

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Effect of pore generator on microstructure and resistivity of Sb2O3 and CuO doped SnO2 electrodes

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dc.contributor.author Sánchez-Rivera, M.-J. es_ES
dc.contributor.author Gozalbo, A. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.contributor.author Mestre, S. es_ES
dc.date.accessioned 2021-07-31T03:30:44Z
dc.date.available 2021-07-31T03:30:44Z
dc.date.issued 2020-12 es_ES
dc.identifier.issn 1380-2224 es_ES
dc.identifier.uri http://hdl.handle.net/10251/171116
dc.description.abstract [EN] Sb(2)O(3)and CuO doped SnO(2)ceramic electrodes could be an alternative to the ones currently used ones in the electrooxidation process of water pollutants. The rise of electrode surface by introducing a porogen agent on the composition was analysed in order to increase the electrochemical active surface. For this reason, several substances were tested. Although the densification and total pore volume had similar values, the microstructures and the pore size distributions generated were strongly dependent on porogen nature. A total of five porogens were tested, but petroleum coke turned out to be the best option for these electrodes. It was found that the electrical resistivity depends on the nature of pore generator. Furthermore, its relation to the porosity can be modelled with Archie's or Pabst's equations. es_ES
dc.description.sponsorship The authors are very grateful to the Ministerio de Economia y Competitividad (Projects: CTQ2015-65202-C2-1-R and CTQ2015-65202-C2-2-R) and to the European Regional Development Fund (FEDER), for their economic support. es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation MINISTERIO DE ECONOMIA Y EMPRESA/CTQ2015-65202-C2-1-R es_ES
dc.relation.ispartof Journal of Porous Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electrode es_ES
dc.subject Sintering es_ES
dc.subject Porosity es_ES
dc.subject Microstructure es_ES
dc.subject Electrical conductivity es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Effect of pore generator on microstructure and resistivity of Sb2O3 and CuO doped SnO2 electrodes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10934-020-00959-0 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-1-R/ES/CARACTERIZACION ELECTROQUIMICA DE ELECTRODOS CERAMICOS Y APLICACION A PROCESOS ELECTROQUIMICOS DE OXIDACION AVANZADA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Sánchez-Rivera, M.; Gozalbo, A.; Pérez-Herranz, V.; Mestre, S. (2020). Effect of pore generator on microstructure and resistivity of Sb2O3 and CuO doped SnO2 electrodes. Journal of Porous Materials. 27(6):1801-1808. https://doi.org/10.1007/s10934-020-00959-0 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s10934-020-00959-0 es_ES
dc.description.upvformatpinicio 1801 es_ES
dc.description.upvformatpfin 1808 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 27 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\423544 es_ES
dc.contributor.funder MINISTERIO DE ECONOMIA Y EMPRESA es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.description.references C.A. Martínez-Huitle, S. Ferro, Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes. Chem. Soc. Rev. 35, 1324–1340 (2006). https://doi.org/10.1039/B517632H es_ES
dc.description.references C.A. Kent, J.J. Concepcion, C.J. Dares, D.A. Torelli, A.J. Rieth, A.S. Miller, P.G. Hoertz, T.J. Meyer, Water oxidation and oxygen monitoring by cobalt-modified fluorine-doped tin oxide electrodes. J. Am. Chem. Soc. 135, 8432–8435 (2013). https://doi.org/10.1021/ja400616a es_ES
dc.description.references M.P. Miranda, R. Del Rio, M.A. Del Valle, M. Faundez, F. Armijo, Use of fluorine-doped tin oxide electrodes for lipoic acid determination in dietary supplements. J. Electroanal. Chem. 668, 1–6 (2012). https://doi.org/10.1016/j.jelechem.2011.12.022 es_ES
dc.description.references M.A.Q. Alfaro, S. Ferro, C.A. Martínez-Huitle, Y.M. Vong, Boron doped diamond electrode for the wastewater treatment. J. Braz. Chem. Soc. 17, 227–236 (2006). https://doi.org/10.1590/S0103-50532006000200003 es_ES
dc.description.references J. Mora-Gómez, M. García-Gabaldón, E. Ortega, M.-J. Sánchez-Rivera, S. Mestre, V. Pérez-Herranz, Evaluation of new ceramic electrodes based on Sb-doped SnO2 for the removal of emerging compounds present in wastewater. Ceram. Int. 44, 2216–2222 (2018). https://doi.org/10.1016/j.ceramint.2017.10.178 es_ES
dc.description.references C.J. Evans, Industrial uses of tin chemicals, Chem. Tin, Springer Netherlands, Dordrecht, 1998: pp. 442–479. https://doi.org/10.1007/978-94-011-4938-9_12 es_ES
dc.description.references J. Molera, T. Pradell, N. Salvadó, M. Vendrell-Saz, Evidence of tin oxide recrystallization in opacified lead glazes. J. Am. Ceram. Soc. 82, 2871–2875 (2004). https://doi.org/10.1111/j.1151-2916.1999.tb02170.x es_ES
dc.description.references P.P. Tsai, I.-C. Chen, M.H. Tzeng, Tin oxide (SnOX) carbon monoxide sensor fabricated by thick-film methods. Sensors Actuators B 25, 537–539 (1995). https://doi.org/10.1016/0925-4005(95)85116-X es_ES
dc.description.references F. Li, J. Xu, X. Yu, L. Chen, J. Zhu, Z. Yang, X. Xin, One-step solid-state reaction synthesis and gas sensing property of tin oxide nanoparticles. Sensors Actuators B 165–169. http://www.sciencedirect.com/science/article/pii/S0925400501009479 es_ES
dc.description.references S. Zuca, M. Terzi, M. Zaharescu, K. Matiasovsky, Contribution to the study of SnO2-based ceramics. J. Mater. Sci. 26, 1673–1676 (1991). https://doi.org/10.1007/BF00544681 es_ES
dc.description.references M. BATZILL, U. DIEBOLD, The surface and materials science of tin oxide. Prog. Surf. Sci. 79, 47–154 (2005). https://doi.org/10.1016/j.progsurf.2005.09.002 es_ES
dc.description.references G. Monrós. El color de la cerámica: nuevos mecanismos en pigmentos para los nuevos procesados de la industria cerámica, n.d. https://books.google.es/books/about/El_Color_de_la_cerámica.html?id=yfIogcGvdqUC&redir_esc=y . Accessed 29 Aug 2018 es_ES
dc.description.references E.R. Leite, J.A. Cerri, E. Longo, J.A. Varela, C.A. Paskocima, Sintering of ultrafine undoped SnO2 powder. J. Eur. Ceram. Soc. 21, 669–675 (2001). https://doi.org/10.1016/S0955-2219(00)00250-8 es_ES
dc.description.references S. Mihaiu, O. Scarlat, G. Aldica, M. Zaharescu, SnO2 electroceramics with various additives. J. Eur. Ceram. Soc. 21, 1801–1804 (2001). https://doi.org/10.1016/S0955-2219(01)00119-4 es_ES
dc.description.references C.R. Foschini, L. Perazolli, J.A. Varela, Sintering of tin oxide using zinc oxide as a densification aid. J. Mater. Sci. 39, 5825–5830 (2004). https://doi.org/10.1023/B:JMSC.0000040095.03906.61 es_ES
dc.description.references M.S. Castro, C.M. Aldao, Characterization of SnO2-varistors with different additives. J. Eur. Ceram. Soc. 18, 2233–2239 (1998). https://doi.org/10.1016/S0955-2219(97)00130-1 es_ES
dc.description.references A.-M. Popescu, S. Mihaiu, S. Zuca, Microstructure and electrochemical behaviour of some SnO2-based inert electrodes in aluminium electrolysis. Zeitschrift Für Naturforsch. A 57, 71–75 (2002). https://doi.org/10.1515/zna-2002-1-210 es_ES
dc.description.references M.R. Sahar, M. Hasbullah, Properties of SnO2-based ceramics. 30, 5304–5305 (1995) es_ES
dc.description.references D. Nisiro, G. Fabbri, G.C. Celotti, A. Bellosi, Influence of the additives and processing conditions on the characteristics of dense SnO2-based ceramics. J. Mater. Sci. 38, 2727–2742 (2003). https://doi.org/10.1023/A:1024459307992 es_ES
dc.description.references M.-J. Sánchez-Rivera, CuO improved (Sn,Sb)O2 ceramic anodes for electrochemical advanced oxidation processes. Int. J. Appl. Ceram. Technol. (2018) es_ES
dc.description.references B. Das, B. Chakrabarty, P. Barkakati, Preparation and characterization of novel ceramic membranes for micro-filtration applications. Ceram. Int. 42, 14326–14333 (2016). https://doi.org/10.1016/j.ceramint.2016.06.125 es_ES
dc.description.references I. Hedfi, N. Hamdi, M.A. Rodriguez, E. Srasra, Development of a low cost micro-porous ceramic membrane from kaolin and Alumina, using the lignite as porogen agent. Ceram. Int. 42, 5089–5093 (2016). https://doi.org/10.1016/j.ceramint.2015.12.023 es_ES
dc.description.references M. García-Gabaldón, V. Pérez-Herranz, E. Sánchez, S. Mestre, Effect of porosity on the effective electrical conductivity of different ceramic membranes used as separators in eletrochemical reactors. J. Memb. Sci. 280, 536–544 (2006). https://doi.org/10.1016/j.memsci.2006.02.007 es_ES
dc.description.references J.-H. Kim, K.-H. Lee, Effect of PEG additive on membrane formation by phase inversion. J. Memb. Sci. 138, 153–163 (1998). https://doi.org/10.1016/S0376-7388(97)00224-X es_ES
dc.description.references B.K. Nandi, R. Uppaluri, M.K. Purkait, Preparation and characterization of low cost ceramic membranes for micro-filtration applications. Appl. Clay Sci. 42, 102–110 (2008). https://doi.org/10.1016/j.clay.2007.12.001 es_ES
dc.description.references F. Bouzerara, A. Harabi, S. Condom, Porous ceramic membranes prepared from kaolin. Desalin. Water Treat. 12, 415–419 (2009). https://doi.org/10.5004/dwt.2009.1051 es_ES
dc.description.references Q. Guibao, L. Tengfei, W. Jian, B. Chenguang, Preparation Titanium Foams with Uniform and Fine Pore Characteristics Through Powder Route Using Urea Particles as Space Holder (Springer, Cham, 2018), pp. 861–868. https://doi.org/10.1007/978-3-319-72526-0_82 es_ES
dc.description.references K. Zou, Y. Deng, J. Chen, Y. Qian, Y. Yang, Y. Li, G. Chen, Hierarchically porous nitrogen-doped carbon derived from the activation of agriculture waste by potassium hydroxide and urea for high-performance supercapacitors. J. Power Sources. 378, 579–588 (2018). https://doi.org/10.1016/j.jpowsour.2017.12.081 es_ES
dc.description.references S. Vijayan, R. Narasimman, K. Prabhakaran, A urea crystal templating method for the preparation of porous alumina ceramics with the aligned pores. J. Eur. Ceram. Soc. 33, 1929–1934 (2013). https://doi.org/10.1016/j.jeurceramsoc.2013.02.031 es_ES
dc.description.references R.M. German, Sintering Theory and Practice (Wiley, New York, 1996) es_ES
dc.description.references G.E. Archie, The electrical resistivity log as an aid in determining some reservoir characteristics. Trans. AIME. 146, 54–62 (1942) es_ES
dc.description.references P. WAGNER, J.A. O’ROURKE, P.E. ARMSTRONG, Porosity effects in polycrystalline graphite. J. Am. Ceram. Soc. 55, 214–219 (1972). https://doi.org/10.1111/j.1151-2916.1972.tb11262.x es_ES
dc.description.references H.El Khal, A. Cordier, N. Batis, E. Siebert, S. Georges, M.C. Steil, Effect of porosity on the electrical conductivity of LAMOX materials. Solid State Ionics. 304, 75–84 (2017). https://doi.org/10.1016/j.ssi.2017.03.028 es_ES
dc.description.references S. Tian-Ming, D. Li-Min, W. Chen, G. Wen-Li, W. Li, T.-X. Liang, New carbon materials Effect of porosity on the electrical resistivity of carbon materials. New Carbon Mater 28, 349–354 (2013). https://doi.org/10.1016/S1872-5805(13)60087-6 es_ES
dc.description.references W. Pabst, E. Gregorová, Conductivity of porous materials with spheroidal pores. J. Eur. Ceram. Soc. 34, 2757–2766 (2014). https://doi.org/10.1016/j.jeurceramsoc.2013.12.040 es_ES


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