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Design of stable mixed-metal MIL-101(Cr/Fe) materials with enhanced catalytic activity for the Prins reaction

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Design of stable mixed-metal MIL-101(Cr/Fe) materials with enhanced catalytic activity for the Prins reaction

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dc.contributor.author Vallés-García, Cristina es_ES
dc.contributor.author Gkaniatsou, Effrosyni es_ES
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Giménez-Marqués, Mónica es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Greneche, Jean-Marc es_ES
dc.contributor.author Steunou, Nathalie es_ES
dc.contributor.author Sicard, Clemence es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Serre, Christian es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-09-09T03:35:35Z
dc.date.available 2021-09-09T03:35:35Z
dc.date.issued 2020-09-07 es_ES
dc.identifier.issn 2050-7488 es_ES
dc.identifier.uri http://hdl.handle.net/10251/171688
dc.description.abstract [EN] This work highlights the benefit of designing mixed-metal (Cr/Fe) MOFs for enhanced chemical stability and catalytic activity. A robust and stable mixed-metal MIL-101(Cr/Fe) was prepared through a HF-free direct hydrothermal route with Fe(3+)content up to 21 wt%. The incorporation of Fe(3+)cations in the crystal structure was confirmed by(57)Fe Mossbauer spectrometry. The catalytic performance of the mixed metal MIL-101(Cr/Fe) was evaluated in the Prins reaction. MIL-101(Cr/Fe) exhibited a higher catalytic activity compared to MIL-101(Cr), improved chemical stability compared to MIL-101(Fe) and a higher catalytic activity for bulky substrates compared to MIL-100(Fe).In situinfra-red spectroscopy study suggests that the incorporation of Fe(3+)ions in MIL-101 structure leads to an increase in Lewis acid sites. It was thus concluded that the predominant role of Cr(3+)ions was to maintain the crystal structure, while Fe(3+)ions enhanced the catalytic activity. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, CTQ2018-890237-CO2-R1 and Maria de Maeztu, CEX2019-000919-M), is gratefully acknowledged. Generalidad Valenciana is also thanked for funding (Prometeo 2017/083). S. N. thanks financial support by the Ministerio de Ciencia, Innovacion y Universidades (RTI 2018-099482-A-I00 project), Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), and Generalitat Valenciana grupos de investigacion consolidables 2019 (ref: AICO/2019/214) project. E. G. thanks the ANR-11-LABEX-0039 (LabEx CHARM3AT) for financial support. M. G.-M thanks support from "la Caixa" Foundation (LCF/BQ/PI19/11690022) and Generalitat Valenciana (SEJI/2020/036). es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation MINECO/RTI2018-890237-CO2-R1 es_ES
dc.relation.ispartof Journal of Materials Chemistry A es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Design of stable mixed-metal MIL-101(Cr/Fe) materials with enhanced catalytic activity for the Prins reaction es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0ta02991b es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//CEX2019-000919-M/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ANR//ANR-11-LABX-0039/FR/CHimie des ARchitectures MoléculairesMultifonctionnelles et des MATériaux/CHARMMMAT/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Fundació Bancària Caixa d'Estalvis i Pensions de Barcelona//LCF%2FBQ%2FPI19%2F11690022/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//SEJI%2F2019%2F017/ES/ACTIVA: ALTERACIONES DE LA CONSCIENCIA. PROTOCOLOS DE INTERVENCIÓN Y VALORACIÓN ACTIVA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F214/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Vallés-García, C.; Gkaniatsou, E.; Santiago-Portillo, A.; Giménez-Marqués, M.; Alvaro Rodríguez, MM.; Greneche, J.; Steunou, N.... (2020). Design of stable mixed-metal MIL-101(Cr/Fe) materials with enhanced catalytic activity for the Prins reaction. Journal of Materials Chemistry A. 8(33):17002-17011. https://doi.org/10.1039/d0ta02991b es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0ta02991b es_ES
dc.description.upvformatpinicio 17002 es_ES
dc.description.upvformatpfin 17011 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 33 es_ES
dc.relation.pasarela S\430055 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agence Nationale de la Recherche, Francia es_ES
dc.contributor.funder Fundació Bancària Caixa d'Estalvis i Pensions de Barcelona es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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