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Treatment of Cyanide-Free Wastewater from Brass Electrodeposition with EDTA by Electrodialysis: Evaluation of Underlimiting and Overlimiting Operations

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Treatment of Cyanide-Free Wastewater from Brass Electrodeposition with EDTA by Electrodialysis: Evaluation of Underlimiting and Overlimiting Operations

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dc.contributor.author Santana Barros, Kayo es_ES
dc.contributor.author Scarazzato, Tatiana es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.contributor.author Espinosa, Denise Crocce Romano es_ES
dc.date.accessioned 2021-09-14T03:33:11Z
dc.date.available 2021-09-14T03:33:11Z
dc.date.issued 2020-04 es_ES
dc.identifier.uri http://hdl.handle.net/10251/172301
dc.description.abstract [EN] Growing environmental concerns have led to the development of cleaner processes, such as the substitution of cyanide in electroplating industries and changes in the treatment of wastewaters. Hence, we evaluated the treatment of cyanide-free wastewater from the brass electroplating industry with EDTA as a complexing agent by electrodialysis, aimed at recovering water and concentrated solutions for reuse. The electrodialysis tests were performed in underlimiting and overlimiting conditions. The results suggested that intense water dissociation occurred at the cathodic side of the commercial anion-exchange membrane (HDX) during the overlimiting test. Consequently, the pH reduction at this membrane may have led to the reaction of protons with complexes of EDTA-metals and insoluble species. This allowed the migration of free Cu2+ and Zn2+ to the cation-exchange membrane as a result of the intense electric field and electroconvection. These overlimiting phenomena accounted for the improvement of the percent extraction and percent concentration, since in the electrodialysis stack employed herein, the concentrate compartments of cationic and anionic species were connected to the same reservoir. Chronopotentiometric studies showed that electroconvective vortices minimized fouling/scaling at both membranes. The electrodialysis in the overlimiting condition seemed to be more advantageous due to water dissociation and electroconvection. es_ES
dc.description.sponsorship This research was funded by CNPq (Process 141346/2016-7 and 171241/2017-7), FAPESP (Process 2012/51871-9) and CAPES (Processes 88881.190502/2018-01 and 88887.362657/2019-00). This study was financed in part by the Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior-Brasil (CAPES)-Finance Code 001. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Membranes es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Electrodialysis es_ES
dc.subject Chronopotentiometry es_ES
dc.subject Ion-exchange membrane es_ES
dc.subject Overlimiting current es_ES
dc.subject Water dissociation es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Treatment of Cyanide-Free Wastewater from Brass Electrodeposition with EDTA by Electrodialysis: Evaluation of Underlimiting and Overlimiting Operations es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/membranes10040069 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CNPq//171241%2F2017-7/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FAPESP//2012%2F51871-9/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//88887.362657%2F2019-00/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//001/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CNPq//141346%2F2016-7/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//88881.190502%2F2018-01/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Santana Barros, K.; Scarazzato, T.; Pérez-Herranz, V.; Espinosa, DCR. (2020). Treatment of Cyanide-Free Wastewater from Brass Electrodeposition with EDTA by Electrodialysis: Evaluation of Underlimiting and Overlimiting Operations. Membranes. 10(4):1-21. https://doi.org/10.3390/membranes10040069 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/membranes10040069 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 21 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 4 es_ES
dc.identifier.eissn 2077-0375 es_ES
dc.identifier.pmid 32290497 es_ES
dc.identifier.pmcid PMC7231372 es_ES
dc.relation.pasarela S\413603 es_ES
dc.contributor.funder Fundação de Amparo à Pesquisa do Estado de São Paulo es_ES
dc.contributor.funder Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil es_ES
dc.contributor.funder Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil es_ES
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