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Valorization of Linen Processing By-Products for the Development of Injection-Molded Green Composite Pieces of Polylactide with Improved Performance

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Valorization of Linen Processing By-Products for the Development of Injection-Molded Green Composite Pieces of Polylactide with Improved Performance

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dc.contributor.author Agüero, Ángel es_ES
dc.contributor.author Lascano-Aimacaña, Diego Sebastián es_ES
dc.contributor.author Garcia-Sanoguera, David es_ES
dc.contributor.author Fenollar, Octavio es_ES
dc.contributor.author Torres Giner, Sergio es_ES
dc.date.accessioned 2021-09-16T03:31:48Z
dc.date.available 2021-09-16T03:31:48Z
dc.date.issued 2020-01-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/172596
dc.description.abstract [EN] This work reports the development and characterization of green composites based on polylactide (PLA) containing fillers and additives obtained from by-products or waste-streams from the linen processing industry. Flaxseed flour (FSF) was first produced by the mechanical milling of golden flaxseeds. The resultant FSF particles were melt-compounded at 30 wt% with PLA in a twin-screw extruder. Two multi-functionalized oils derived from linseed, namely epoxidized linseed oil (ELO) and maleinized linseed oil (MLO), were also incorporated during melt mixing at 2.5 and 5 parts per hundred resin (phr) of composite. The melt-compounded pellets were thereafter shaped into pieces by injection molding and characterized. Results showed that the addition of both multi-functionalized linseed oils successfully increased ductility, toughness, and thermal stability of the green composite pieces whereas water diffusion was reduced. The improvement achieved was related to both a plasticizing effect and, more interestingly, an enhancement of the interfacial adhesion between the biopolymer and the lignocellulosic particles by the reactive vegetable oils. The most optimal performance was attained for the MLO-containing green composite pieces, even at the lowest content, which was ascribed to the higher solubility of MLO with the PLA matrix. Therefore, the present study demonstrates the potential use of by-products or waste from flax (Linum usitatissimum L.) to obtain renewable raw materials of suitable quality to develop green composites with high performance for market applications such as rigid food packaging and food-contact disposable articles in the frame of the Circular Economy and Bioeconomy. es_ES
dc.description.sponsorship This research work was funded by the Spanish Ministry of Science, Innovation, and Universities (MICIU) project numbers RTI2018-097249-B-C21 and MAT2017-84909-C2-2-R. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Sustainability es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject PLA es_ES
dc.subject Flax es_ES
dc.subject Multi-functionalized vegetable oils es_ES
dc.subject Green composites es_ES
dc.subject Waste valorization es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification TECNOLOGIA DE ALIMENTOS es_ES
dc.title Valorization of Linen Processing By-Products for the Development of Injection-Molded Green Composite Pieces of Polylactide with Improved Performance es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/su12020652 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-097249-B-C21/ES/ENVASE ACTIVO MULTICAPA TERMOCONFORMABLE DE ALTA BARRERA BASADO EN BIOECONOMIA CIRCULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Agüero, Á.; Lascano-Aimacaña, DS.; Garcia-Sanoguera, D.; Fenollar, O.; Torres Giner, S. (2020). Valorization of Linen Processing By-Products for the Development of Injection-Molded Green Composite Pieces of Polylactide with Improved Performance. Sustainability. 12(2):1-24. https://doi.org/10.3390/su12020652 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/su12020652 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 24 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2071-1050 es_ES
dc.relation.pasarela S\427471 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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dc.subject.ods 12.- Garantizar las pautas de consumo y de producción sostenibles es_ES


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