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dc.contributor.author | Tejada-Oliveros, Ramon![]() |
es_ES |
dc.contributor.author | Gómez-Caturla, Jaume![]() |
es_ES |
dc.contributor.author | Sanchez-Nacher, Lourdes![]() |
es_ES |
dc.contributor.author | Montanes, Nestor![]() |
es_ES |
dc.contributor.author | Quiles-Carrillo, Luis![]() |
es_ES |
dc.date.accessioned | 2022-01-21T19:03:40Z | |
dc.date.available | 2022-01-21T19:03:40Z | |
dc.date.issued | 2021-12 | es_ES |
dc.identifier.issn | 1438-7492 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/180092 | |
dc.description.abstract | [EN] This work reports on the development of polylactide (PLA) and polycarbonate (PC) blends with different compatibilizers with enhanced toughness. Since both polymers are immiscible, two types of compatibilizers are tested: petrochemical-based copolymers Xibond 160 and Xibond 920 with maleic anhydride and epoxy groups, respectively, and natural-based compatibilizers with the same functionalities, namely maleinized linseed oil (MLO) and, epoxidized linseed oil (ELO). Mechanical, thermal, and morphological characterization shows better properties for the PLA/PC (80/20 wt%) blends with chemically modified natural oils (ELO and MLO). The addition of 5 phr (parts per hundred resin) of MLO gives the maximum values for impact strength and elongation at break. Moreover, the glass transition temperature (Tg) slightly decreases with the addition of natural compatibilizers, thus showing some plasticization effect. Petroleum-derived compatibilizers give interesting results regarding tensile strength and stiffness without plasticization. PLA/PC blends show higher thermal stability than neat PLA, regardless of the compatibilizer used, since PC is much more thermally stable than PLA. The obtained results indicate that both petroleum-based and natural-derived compatibilizers positively contribute to enhance the properties of the binary PLA/PC blends. Nevertheless, the results with MLO suggest this is an interesting biobased solution to provide increased toughness to PLA/PC blends. | es_ES |
dc.description.sponsorship | L.Q.-C. wants to thank Universitat Politècnica de València for his postdoctoral PAID-10-20 grant from (SP20200073). J.G.-C. wants to thank Universitat Politècnica de València for his FPI grant from (SP20200080). This research was funded by the Ministry of Science, Innovation, and Universities (MICIU) project number MAT2017-84909-C2-2-R. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Macromolecular Materials and Engineering | es_ES |
dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
dc.subject | Biopolymers | es_ES |
dc.subject | Mechanical properties | es_ES |
dc.subject | Polylactide | es_ES |
dc.subject | Toughness | es_ES |
dc.subject.classification | CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA | es_ES |
dc.title | Improved Toughness of Polylactide by Binary Blends with Polycarbonate with Glycidyl and Maleic Anhydride-Based Compatibilizers | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/mame.202100480 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//SP20200080/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//SP20200073/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//PAID-10-20/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//MAT2017-84909-C2-2-R//PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials | es_ES |
dc.description.bibliographicCitation | Tejada-Oliveros, R.; Gómez-Caturla, J.; Sanchez-Nacher, L.; Montanes, N.; Quiles-Carrillo, L. (2021). Improved Toughness of Polylactide by Binary Blends with Polycarbonate with Glycidyl and Maleic Anhydride-Based Compatibilizers. Macromolecular Materials and Engineering. 306(12):1-11. https://doi.org/10.1002/mame.202100480 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/mame.202100480 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 11 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 306 | es_ES |
dc.description.issue | 12 | es_ES |
dc.relation.pasarela | S\452188 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |
dc.subject.ods | 09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación | es_ES |
dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |