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Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks

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Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks

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dc.contributor.author Salmerón Sánchez, Manuel es_ES
dc.contributor.author Molina Mateo, José es_ES
dc.contributor.author Romero Colomer, Francisco Jose es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.date.accessioned 2022-03-22T19:02:28Z
dc.date.available 2022-03-22T19:02:28Z
dc.date.issued 2006-06 es_ES
dc.identifier.issn 0014-3057 es_ES
dc.identifier.uri http://hdl.handle.net/10251/181502
dc.description.abstract [EN] According to our previous results the free radical copolymerization of ethyl acrylate and hydroxyethyl methacrylate gives rise to a system having chain composition and morphology different from that of the random mixture in the original solution. Besides, structural relaxation experiments revealed the existence of composition heterogeneity in the material. In this work, a deeper insight in the structure of this system is gained using atomic force microscopy (AFM) in the tapping mode and nanoindentation experiments. The material architecture of the copolymerized system is revealed to be formed by nanoaggregates as a consequence of the non-random polymerization process of the comonomers. (c) 2006 Elsevier Ltd. All rights reserved. es_ES
dc.description.sponsorship The authors acknowledge the support of the Spanish Science and Technology Ministry through the MAT2001-2678-C02-01 project and the support to their research group by the Generalitat Valenciana through the Grupos 03/018 project. AFM was conducted by the microscopy service of the UPV, whose advice was greatly appreciated es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation GENERALITAT VALENCIANA//GRUPOS03%2F018//AYUDA AL GRUPO: CENTRO DE BIOMATERIALES / es_ES
dc.relation.ispartof European Polymer Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Nanoindentation es_ES
dc.subject AFM es_ES
dc.subject Copolymers es_ES
dc.subject Nanophase separation es_ES
dc.title Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.eurpolymj.2005.12.018 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINISTERIO DE CIENCIA Y TECNOLOGIA//MAT2001-2678-C02-01//SOPORTES POLIMERICOS MACROPOROSOS PARA REGENERACION DEL CARTILAGO ARTICULAR CON TECNICAS DE INGENIERIA DE TEJIDOS/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.description.bibliographicCitation Salmerón Sánchez, M.; Molina Mateo, J.; Romero Colomer, FJ.; Gómez Ribelles, JL. (2006). Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks. European Polymer Journal. 42(6):1378-1383. https://doi.org/10.1016/j.eurpolymj.2005.12.018 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.eurpolymj.2005.12.018 es_ES
dc.description.upvformatpinicio 1378 es_ES
dc.description.upvformatpfin 1383 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 42 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\29995 es_ES
dc.contributor.funder MINISTERIO DE CIENCIA Y TECNOLOGIA es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES


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