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dc.contributor.author | Tejeda-Serrano, Maria | es_ES |
dc.contributor.author | Lloret, Vicent | es_ES |
dc.contributor.author | Markus, Bence G. | es_ES |
dc.contributor.author | Simon, Ferenc | es_ES |
dc.contributor.author | Hauke, Frank | es_ES |
dc.contributor.author | Hirsch, Andreas | es_ES |
dc.contributor.author | Doménech-Carbó, Antonio | es_ES |
dc.contributor.author | Abellán Sáez, Gonzalo | es_ES |
dc.contributor.author | Leyva Perez, Antonio | es_ES |
dc.date.accessioned | 2022-05-31T18:04:30Z | |
dc.date.available | 2022-05-31T18:04:30Z | |
dc.date.issued | 2020-04-20 | es_ES |
dc.identifier.issn | 1867-3880 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/183006 | |
dc.description.abstract | [EN] The substitution of catalytic metals by p-block main elements has a tremendous impact not only in the fundamentals but also in the economic and ecological fingerprint of organic reactions. Here we show that few-layer black phosphorous (FL-BP), a recently discovered and now readily available 2D material, catalyzes different radical additions to alkenes with an initial turnover frequency (TOF0) up to two orders of magnitude higher than representative state-of-the-art metal complex catalysts at room temperature. The corresponding electron-rich BP intercalation compound (BPIC) KP6 shows a nearly twice TOF0 increase with respect to FL-BP. This increase in catalytic activity respect to the neutral counterpart also occurs in other 2D materials (graphene vs. KC8) and metal complex catalysts (Fe-0 vs. Fe2- carbon monoxide complexes). This reactive parallelism opens the door for cross-fertilization between 2D materials and metal catalysts in organic synthesis. | es_ES |
dc.description.sponsorship | We thank the European Research Council (ERC Starting Grant 2D-PnictoChem 804110 to G.A. and ERC Advanced Grant 742145 B-PhosphoChem to A.H.). G.A. thanks the financial support from the Spanish MINECO and iDiFEDER/2018/061 co-financed by FEDER (Unit of Excellence "Maria de Maeztu" MDM-2015-0538), the Generalitat Valenciana (CIDEGENT/2018/001 grant), and the Deutsche Forschungsgemeinschaft (DFG, FLAG-ERA AB694/2-1). M. T.-S. thanks ITQ for a contract. A. L.-P. thanks financial support by MINECO (Spain) (Projects CTQ 2014-55178-R, CTQ 2017-86735-P and Excellence Unit "Severo Ochoa" SEV-2016-0683) and also "Convocatoria 2014 de Ayudas Fundacion BBVA a Investigadores y Creadores Culturales". B. G. M. and F. S. were supported by the National Research, Development and Innovation Office of Hungary (NKFIH) Grant Nrs. K119442 and 2017-1.2.1-NKP-2017-00001. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | ChemCatChem | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Black phosphorus | es_ES |
dc.subject | P-block catalysis | es_ES |
dc.subject | Radical addition | es_ES |
dc.subject | Alkenes | es_ES |
dc.subject | Iron | es_ES |
dc.subject | 2D materials | es_ES |
dc.title | Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/cctc.201902276 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/NKFIH//K119442/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-86735-P/ES/CATALISIS CON ATOMOS METALICOS AISLADOS Y CLUSTERES ULTRAPEQUEÑOS BIEN DEFINIDOS, SIN LIGANDOS Y CONFINADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/NKFIH//2017-1.2.1-NKP-2017-00001/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/742145/EU | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MDM-2015-0538//INSTITUTO DE CIENCIA MOLECULAR/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/804110/EU | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MCIU//SEV-2016-0683/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2014-55178-R/ES/HIERRO Y BISMUTO SUB-NANOMETRICO Y CATALITICO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//CIDEGENT%2F2018%2F001/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/DFG//FLAG-ERA AB694%2F2-1/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Tejeda-Serrano, M.; Lloret, V.; Markus, BG.; Simon, F.; Hauke, F.; Hirsch, A.; Doménech-Carbó, A.... (2020). Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals. ChemCatChem. 12(8):2226-2232. https://doi.org/10.1002/cctc.201902276 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/cctc.201902276 | es_ES |
dc.description.upvformatpinicio | 2226 | es_ES |
dc.description.upvformatpfin | 2232 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 12 | es_ES |
dc.description.issue | 8 | es_ES |
dc.identifier.pmid | 32421028 | es_ES |
dc.identifier.pmcid | PMC7216949 | es_ES |
dc.relation.pasarela | S\461661 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Deutsche Forschungsgemeinschaft | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades | es_ES |
dc.contributor.funder | National Research, Development and Innovation Office, Hungría | es_ES |