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Influence of boron promotion on the physico-chemical properties and catalytic behavior of Zn/ZSM-5 in the aromatization of n-hexane

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Influence of boron promotion on the physico-chemical properties and catalytic behavior of Zn/ZSM-5 in the aromatization of n-hexane

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dc.contributor.author Huyen, Pham Thanh es_ES
dc.contributor.author Trinh, Vu Dinh es_ES
dc.contributor.author Portilla, M. Teresa es_ES
dc.contributor.author Martínez, Cristina es_ES
dc.date.accessioned 2022-05-31T18:04:47Z
dc.date.available 2022-05-31T18:04:47Z
dc.date.issued 2021-04-15 es_ES
dc.identifier.issn 0920-5861 es_ES
dc.identifier.uri http://hdl.handle.net/10251/183014
dc.description.abstract [EN] The characterization and catalytic performance of Zn/ZSM-5 and Zn-B/ZSM-5 catalysts in the n-hexane aromatization was reported. Catalysts were prepared by post-synthesis ion exchange and thoroughly characterized by means of XRD, Py-FTIR, N-2 adsorption, Al-27 and B-11 MAS NMR spectroscopy and electron microscopy techniques. The incorporation of zinc reduces the Bronsted acid site density and increases the Lewis acidic sites of the final ZSM-5 based catalysts. The presence of boron slightly reduces the initial activity of the catalyst but slows down its deactivation rate. es_ES
dc.description.sponsorship This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant number 104.05-2018.306, M.T. Portilla and C. Martinez acknowledge support by the Spanish Government-MICINN through 'Severo Ochoa"(SEV-2016-0683) and RTI2018-101033-B-I00, by the Fundacion Ramon Areces through a research contract of the "Life and Materials Science" program, and by Generalitat Valenciana through AICO/2019/060. The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization. We thank E. Briz for technical assistance. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Catalysis Today es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Aromatization es_ES
dc.subject Pyridin FTIR es_ES
dc.subject Zn-modified ZSM-5 zeolite es_ES
dc.subject Boron promoter es_ES
dc.title Influence of boron promotion on the physico-chemical properties and catalytic behavior of Zn/ZSM-5 in the aromatization of n-hexane es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.cattod.2020.03.030 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NAFOSTED//104.05-2018.306/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F060/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Huyen, PT.; Trinh, VD.; Portilla, MT.; Martínez, C. (2021). Influence of boron promotion on the physico-chemical properties and catalytic behavior of Zn/ZSM-5 in the aromatization of n-hexane. Catalysis Today. 366:97-102. https://doi.org/10.1016/j.cattod.2020.03.030 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.cattod.2020.03.030 es_ES
dc.description.upvformatpinicio 97 es_ES
dc.description.upvformatpfin 102 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 366 es_ES
dc.relation.pasarela S\464133 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder National Foundation for Science and Technology Development, Vietnam es_ES


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