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dc.contributor.author | Tejeda-Serrano, Maria | es_ES |
dc.contributor.author | Sanz-Navarro, Sergio | es_ES |
dc.contributor.author | Blake, Finn | es_ES |
dc.contributor.author | Leyva Perez, Antonio | es_ES |
dc.date.accessioned | 2022-06-01T18:07:24Z | |
dc.date.available | 2022-06-01T18:07:24Z | |
dc.date.issued | 2020-07-17 | es_ES |
dc.identifier.issn | 0039-7881 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/183046 | |
dc.description.abstract | [EN] Zeolites are the most used catalysts worldwide in petrochemistry processes, with particular ability to stabilize carbocations. However, the use of zeolites in organic synthesis is still scarce. We show here that representative carboxonium-mediated organic reactions, such as the Nazarov cyclization and thetert-butylation of alcohols withtert-butyl acetate, typically performed with very strong acid catalysts in solution such as triflic acid, can be catalyzed by simple zeolites with high yield and selectivity. The aluminosilicate framework stabilizes the intermediate carboxonium species and overrides the need for superacid protons in solution | es_ES |
dc.description.sponsorship | This work was supported by the MINECO (Spain) (Projects CTQ 2017-86735-P, RTC-2017-6331-5, and Severo Ochoa program SEV-2016-0683) | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Georg Thieme Verlag KG | es_ES |
dc.relation.ispartof | Synthesis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Zeolites | es_ES |
dc.subject | Solid catalyst | es_ES |
dc.subject | Nazarov reaction | es_ES |
dc.subject | Tert-butylation reaction | es_ES |
dc.subject | Carboxonium | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.title | Zeolites Catalyze the Nazarov Reaction and thetert-Butylation of Alcohols by Stabilization of Carboxonium Intermediates | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1055/s-0039-1690896 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-86735-P/ES/CATALISIS CON ATOMOS METALICOS AISLADOS Y CLUSTERES ULTRAPEQUEÑOS BIEN DEFINIDOS, SIN LIGANDOS Y CONFINADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINISTERIO DE CIENCIA, INNOVACIÓN Y UNIVERSIDADES//RTC-2017-6331-5//NUEVA SINTESIS DEL OLIGOMERO CLAVE EN TINTAS DIGITALES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MCIU//SEV-2016-0683/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Tejeda-Serrano, M.; Sanz-Navarro, S.; Blake, F.; Leyva Perez, A. (2020). Zeolites Catalyze the Nazarov Reaction and thetert-Butylation of Alcohols by Stabilization of Carboxonium Intermediates. Synthesis. 52(14):2031-2037. https://doi.org/10.1055/s-0039-1690896 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1055/s-0039-1690896 | es_ES |
dc.description.upvformatpinicio | 2031 | es_ES |
dc.description.upvformatpfin | 2037 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 52 | es_ES |
dc.description.issue | 14 | es_ES |
dc.relation.pasarela | S\461654 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | MINISTERIO DE CIENCIA, INNOVACIÓN Y UNIVERSIDADES | es_ES |