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Fe clusters embedded on N-doped graphene as a photothermal catalyst for selective CO2 hydrogenation

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Fe clusters embedded on N-doped graphene as a photothermal catalyst for selective CO2 hydrogenation

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dc.contributor.author Szalad, Horatiu es_ES
dc.contributor.author Peng, Lu es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2022-06-09T18:06:48Z
dc.date.available 2022-06-09T18:06:48Z
dc.date.issued 2021-10-07 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/183156
dc.description.abstract [EN] In comparison with the Co analog, small Fe clusters incorporated in a graphene matrix exhibit a photo-assisted increase of 110% in reverse water gas shift CO2 hydrogenation under UV-Vis light irradiation. Available data indicate that the photo-assistance derives from light absorption by the N-doped graphene followed by charge recombination at the Fe clusters, increasing their local temperature. es_ES
dc.description.sponsorship L. P. prepared and characterized the catalysts. H. S. performed the photocatalytic reactions and mechanistic experiments. A. P. supervised the materials preparation and characterization. J. A. performed the TA measurements. This work was supervised by J. A. and H. G. who wrote the draft. The manuscript was revised by all the authors. Financial support by the Spanish Ministry of Science and Innovation (RTI201898237-CO2-1) and Generalitat Valenciana (Prometeo 2017-083) is gratefully acknowledged. This project has also received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 861151. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Fe clusters embedded on N-doped graphene as a photothermal catalyst for selective CO2 hydrogenation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d1cc03524j es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2017%2F083//GRAFENOS COMO FOTOELECTRODOS PARA LA GENERACION DE COMBUSTIBLES SOLARES./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/861151/EU es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Szalad, H.; Peng, L.; Primo Arnau, AM.; Albero-Sancho, J.; García Gómez, H. (2021). Fe clusters embedded on N-doped graphene as a photothermal catalyst for selective CO2 hydrogenation. Chemical Communications. 57(78):10075-10078. https://doi.org/10.1039/d1cc03524j es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d1cc03524j es_ES
dc.description.upvformatpinicio 10075 es_ES
dc.description.upvformatpfin 10078 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 57 es_ES
dc.description.issue 78 es_ES
dc.identifier.pmid 34514482 es_ES
dc.relation.pasarela S\446156 es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES
dc.contributor.funder COMISION DE LAS COMUNIDADES EUROPEA es_ES


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