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Bifunctional metal-organic frameworks for the hydrogenation of nitrophenol using methanol as the hydrogen source

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Bifunctional metal-organic frameworks for the hydrogenation of nitrophenol using methanol as the hydrogen source

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dc.contributor.author Melillo, Arianna es_ES
dc.contributor.author García-Vallés, Cristina es_ES
dc.contributor.author Ferrer Ribera, Rosa Belén es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2022-10-03T18:06:09Z
dc.date.available 2022-10-03T18:06:09Z
dc.date.issued 2021-01-28 es_ES
dc.identifier.issn 1477-0520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/186866
dc.description.abstract [EN] This work reports the reduction of 4-nitrophenol to 4-aminophenol using UiO-66(Zr) as a bifunctional photocatalyst and hydrogenation catalyst using methanol as the hydrogen source. In particular, a series of UiO-66(Zr)-X (X: NH2, NO2 and H) and MIL-125(Ti)-NH2 catalysts have been screened as bifunctional catalysts for this process. UiO-66(Zr)-NH2 was found to be the most active material to promote light-assisted nitro hydrogenation under both UV-Vis and simulated sunlight irradiation. The tandem reaction occurs via hydrogen generation from a water/methanol mixture in the first step and, then, reduction of 4-nitrophenol to 4-aminophenol. UiO-66(Zr)-NH2 acts as a truly heterogeneous catalyst and can be reused several times without significant loss of activity, maintaining its crystallinity. This work shows the possibility of using MOFs as solar-driven bifunctional catalysts to promote the hydrogenation of organic compounds using methanol as the hydrogen source. es_ES
dc.description.sponsorship S. N. acknowledges the financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), Ministerio de Ciencia, Innovacion y Universidades RTI 2018-099482-A-I00 project and Generalitat Valenciana grupos de investigacion consolidables 2019 (ref: AICO/2019/214) project. Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and RTI2018-098237-B-C21) and Generalitat Valenciana (Prometeo 2017-083) is also gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Organic & Biomolecular Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Bifunctional metal-organic frameworks for the hydrogenation of nitrophenol using methanol as the hydrogen source es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0ob01686a es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2017%2F083//GRAFENOS COMO FOTOELECTRODOS PARA LA GENERACION DE COMBUSTIBLES SOLARES./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//AICO%2F2019%2F214//MATERIALES CARBONOSOS DE BAJO COSTE COMO CARBOCATALIZADORES SOSTENIBLES EN PROCESOS DE OXIDACION AVANZADA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Melillo, A.; García-Vallés, C.; Ferrer Ribera, RB.; Alvaro Rodríguez, MM.; Navalón Oltra, S.; García Gómez, H. (2021). Bifunctional metal-organic frameworks for the hydrogenation of nitrophenol using methanol as the hydrogen source. Organic & Biomolecular Chemistry. 19(4):794-800. https://doi.org/10.1039/d0ob01686a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0ob01686a es_ES
dc.description.upvformatpinicio 794 es_ES
dc.description.upvformatpfin 800 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 4 es_ES
dc.identifier.pmid 33043920 es_ES
dc.relation.pasarela S\446897 es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES


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