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dc.contributor.author | Ventura, Maria | es_ES |
dc.contributor.author | Mazarío-Santa-Pau, Jaime | es_ES |
dc.contributor.author | Domine, Marcelo Eduardo | es_ES |
dc.date.accessioned | 2022-10-21T18:03:23Z | |
dc.date.available | 2022-10-21T18:03:23Z | |
dc.date.issued | 2022-02-08 | es_ES |
dc.identifier.issn | 1867-3880 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/188562 | |
dc.description.abstract | [EN] This work reports the continuous isomerization of glucose to fructose in aqueous media under mild conditions using a mixed oxide hydrotalcite-derived catalyst based on Ca and Al. Different operational parameters of the continuous flow fix-bed catalytic reactor system were studied. At the optimal conditions, the Ca-Al-based catalyst achieved a very high conversion and almost quantitative selectivity towards fructose, this being one of the few successful examples of a heterogeneous catalyst capable of carrying out this reaction in a continuous process. Importantly, catalytic activity held steady during four hours on stream, and slight deactivation occurring could be practically overcome by thermal regeneration of the catalyst. | es_ES |
dc.description.sponsorship | Grant PGC2018-097277-B-I00 funded by MCIN/AEI/10.13039/501100011033 and "ERDF A way of making Europe", and the financial support by the Spanish Government (SEV-2016-0683) and Generalitat Valenciana (GVA, PROMETEO/2018/006) are gratefully acknowledged. Authors also thank the ITQ for the technical support, and the Electron Microscopy Service of Universitat Politecnica de Valencia for instrumental facilities. J.M. thanks the Spanish Government (CTQ-2015-67592) for his PhD fellowship. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | ChemCatChem | es_ES |
dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
dc.subject | Glucose isomerization | es_ES |
dc.subject | Monosaccharides | es_ES |
dc.subject | Biomass valorization, Continuous process | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.title | Isomerization of Glucose-to-Fructose in Water over a Continuous Flow Reactor using Ca-Al Mixed Oxide as Heterogeneous Catalyst | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/cctc.202101229 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097277-B-I00/ES/MEJORA DEL CONCEPTO DE BIORREFINERIA MEDIANTE IMPLEMENTACION DE NUEVOS PROCESOS CATALITICOS CON CATALIZADORES SOLIDOS DE METALES NO NOBLES PARA LA PRODUCCION DE BIOCOMPUESTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F006//Intensificación de reactores catalíticos para la obtención altamente eficiente de combustibles y productos químicos/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Ventura, M.; Mazarío-Santa-Pau, J.; Domine, ME. (2022). Isomerization of Glucose-to-Fructose in Water over a Continuous Flow Reactor using Ca-Al Mixed Oxide as Heterogeneous Catalyst. ChemCatChem. 14(3):1-8. https://doi.org/10.1002/cctc.202101229 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/cctc.202101229 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 8 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 14 | es_ES |
dc.description.issue | 3 | es_ES |
dc.relation.pasarela | S\463889 | es_ES |
dc.contributor.funder | GVA | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | Ministerio de Economía, Industria y Competitividad | es_ES |
dc.contributor.funder | MINISTERIO DE ASUNTOS ECONOMICOS Y TRANSFORMACION DIGITAL | es_ES |
dc.subject.ods | 09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación | es_ES |
dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |
dc.subject.ods | 13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos | es_ES |