Salcedo-Abraira, P.; Babaryk, AA.; Montero-Lanzuela, E.; Contreras Almengor, OR.; Cabrero-Antonino, M.; Svensson, E.; Willhammar, T.... (2021). A Novel Porous Ti-Squarate as Efficient Photocatalyst in the Overall Water Splitting Reaction under Simulated Sunlight Irradiation. Advanced Materials. 33(52):1-9. https://doi.org/10.1002/adma.202106627
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/189363
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Title:
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A Novel Porous Ti-Squarate as Efficient Photocatalyst in the Overall Water Splitting Reaction under Simulated Sunlight Irradiation
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Author:
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Salcedo-Abraira, Pablo
Babaryk, Artem A.
Montero-Lanzuela, Eva
Contreras Almengor, Oscar R.
Cabrero-Antonino, Maria
Svensson, Erik
Willhammar, Tom
Navalón Oltra, Sergio
Elkäim, Erik
García Gómez, Hermenegildo
Horcajada, Patricia
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Issued date:
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Abstract:
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[EN] A new porous titanium(IV) squarate metal¿organic framework (MOF),
denoted as IEF-11, having a never reported titanium secondary building unit,
is successfully synthesized and fully characterized. IEF-11 not only ...[+]
[EN] A new porous titanium(IV) squarate metal¿organic framework (MOF),
denoted as IEF-11, having a never reported titanium secondary building unit,
is successfully synthesized and fully characterized. IEF-11 not only exhibits
a permanent porosity but also an outstanding chemical stability. Further,
as a consequence of combining the photoactive Ti(IV) and the electroactive
squarate, IEF-11 presents relevant optoelectronic properties, applied here to
the photocatalytic overall water splitting reaction. Remarkably, IEF-11 as a
photocatalyst is able to produce record H2 amounts for MOF-based materials
under simulated sunlight (up to 672 µmol gcatalyst in 22 h) without any activity
loss during at least 10 d.
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Subjects:
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Metal-organic frameworks
,
Porosity
,
Titanium
,
Water splitting photocatalysis
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Copyrigths:
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Reserva de todos los derechos
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Source:
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Advanced Materials. (issn:
0935-9648
)
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DOI:
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10.1002/adma.202106627
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Publisher:
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John Wiley & Sons
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Publisher version:
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https://doi.org/10.1002/adma.202106627
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Project ID:
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info:eu-repo/grantAgreement/AGENCIA VALENCIANA DE LA INNOVACION//INNEST%2F2020%2F111//VALORIZACIÓN DE RESIDUOS DE CARBÓN ACTIVO GRANULAR GENERADOS EN EL PROCESO DE POTABILIZACIÓN COMO CARBOCATALIZADOR SOSTENIBLE EN PROCESOS DE OZONIZACIÓN DEL CICLO INTEGRAL DEL AGUA/
...[+]
info:eu-repo/grantAgreement/AGENCIA VALENCIANA DE LA INNOVACION//INNEST%2F2020%2F111//VALORIZACIÓN DE RESIDUOS DE CARBÓN ACTIVO GRANULAR GENERADOS EN EL PROCESO DE POTABILIZACIÓN COMO CARBOCATALIZADOR SOSTENIBLE EN PROCESOS DE OZONIZACIÓN DEL CICLO INTEGRAL DEL AGUA/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PCI2020-111998/ES/NUEVOS MATERIALES PARA EL DESARROLLO DE ELECTRODOS Y ELECTROLITOS EN PILAS DE COMBUSTIBLE/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104228RB-I00/ES/SEPARACION Y (FOTO)DEGRADACION COMBINADA DE CONTAMINANTES EN AGUA UTILIZANDO DISPOSITIVOS BASADOS EN REDES METAL-ORGANICAS POROSAS/
info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2017%2F083//GRAFENOS COMO FOTOELECTRODOS PARA LA GENERACION DE COMBUSTIBLES SOLARES./
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/
info:eu-repo/grantAgreement/AVI//INNEST%2F2020%2F111/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/
info:eu-repo/grantAgreement/VR//2019-05465/
info:eu-repo/grantAgreement/EC/H2020/730872/EU
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Thanks:
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P.S.-A. and A.A.B. contributed equally to this work. The authors acknowledge the Ramón Areces Foundation project H+MOFs, the M-ERA-NET C-MOF-cell (grant PCI2020-111998 funded by MCIN/AEI/10.13039/501100011033 and European ...[+]
P.S.-A. and A.A.B. contributed equally to this work. The authors acknowledge the Ramón Areces Foundation project H+MOFs, the M-ERA-NET C-MOF-cell (grant PCI2020-111998 funded by MCIN/AEI/10.13039/501100011033 and European Union NextGenerationEU/ PRTR) project, and Retos Investigación MOFSEIDON (grant PID2019-104228RB-I00 funded by MCIN/AEI/10.13039/501100011033) project.
S.N. thanks financial support by Ministerio de Ciencia, Innovatión y Universidades RTI2018-099482-A-I00 project and Agència Valenciana de la Innovació (AVI, INNEST/2020/111) project. H.G. thanks financial support to the Spanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-098237-CO21) and Generalitat Valenciana (Prometeo2017/083). T.W. acknowledges financial support from the Swedish Research Council (VR, 2019-05465). Parts of this research were carried out at ¿CRISTAL¿ at SOLEIL. P.S. and A.A.B. sincerely thank to
the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020 for the support of the synchrotron experiment.
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Type:
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Artículo
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