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Phenyl Extended Naphthalene-Based Covalent Triazine Frameworks as Versatile Metal-Free Heterogeneous Photocatalysts

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Phenyl Extended Naphthalene-Based Covalent Triazine Frameworks as Versatile Metal-Free Heterogeneous Photocatalysts

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dc.contributor.author Fuerte-Diez, Beatriz es_ES
dc.contributor.author Valverde-González, Antonio es_ES
dc.contributor.author Pintado-Sierra, Mercedes es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Sánchez, Félix es_ES
dc.contributor.author Maya, Eva M. es_ES
dc.contributor.author Iglesias, Marta es_ES
dc.date.accessioned 2022-11-10T19:02:39Z
dc.date.available 2022-11-10T19:02:39Z
dc.date.issued 2022-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/189606
dc.description.abstract [EN] Two new covalent triazines frameworks (CTFs) containing phenyl extended naphthalene units (with and without methoxy groups in the naphthalene core) are prepared by thermal and microwave activation. Both procedures yield similar chemical structures combining triazine acceptor units with donor aromatic groups, but they generate some differences in the morphology, structural organization, CO2 adsorption capacity, and thermal and optical properties. Besides, the methoxy groups of the naphthalene core have also influence in some of these properties. The resulting phenyl extended naphthalene CTFs are efficiently utilized as metal-free heterogeneous photocatalyst for the selective aerobic oxidation of sulfides and the dehydrogenative cross-coupling reactions under visible-light irradiation, showing a high chemical stability. es_ES
dc.description.sponsorship The authors acknowledge grants MAT2017-82288-C2-2-P and PID2020-112590GB-C22 funded by MCIN/AEI/10.13039/501100011033 and by "ERDF A way of making Europe". A.V.G. thanks Ministerio de Universidades for FPU17/03463. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Solar RRL es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Covalent triazine frameworks es_ES
dc.subject Extended conjugation es_ES
dc.subject Heterogeneous photocatalysis es_ES
dc.subject Metal-free photocatalysts es_ES
dc.subject Microwave synthesis es_ES
dc.subject Naphthalene moieties es_ES
dc.title Phenyl Extended Naphthalene-Based Covalent Triazine Frameworks as Versatile Metal-Free Heterogeneous Photocatalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/solr.202100848 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-2-P/ES/ESTRATEGIA MODULAR PARA OBTENER ARQUITECTURAS POROSAS MULTIFUNCIONALES PARA REACTIVIDAD A MEDIDA Y OTRAS APLICACIONES NANOTECNOLOGICAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MIU//FPU17%2F03463/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112590GB-C22/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES HECHOS A MEDIDA A PARTIR DE UNIDADES DE CONSTRUCCION SINGULARES: ENFOQUES INTEGRADORES PARA APLICACIONES AMBIENTALES/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Fuerte-Diez, B.; Valverde-González, A.; Pintado-Sierra, M.; Díaz Morales, UM.; Sánchez, F.; Maya, EM.; Iglesias, M. (2022). Phenyl Extended Naphthalene-Based Covalent Triazine Frameworks as Versatile Metal-Free Heterogeneous Photocatalysts. Solar RRL. 6(2):1-10. https://doi.org/10.1002/solr.202100848 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/solr.202100848 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2367-198X es_ES
dc.relation.pasarela S\462286 es_ES
dc.contributor.funder Ministerio de Universidades es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES


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