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Development of hybrid monoliths incorporating metal¿organic frameworks for stir bar sorptive extraction coupled with liquid chromatography for determination of estrogen endocrine disruptors in water and human urine samples

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Development of hybrid monoliths incorporating metal¿organic frameworks for stir bar sorptive extraction coupled with liquid chromatography for determination of estrogen endocrine disruptors in water and human urine samples

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dc.contributor.author Zatrochová, S. es_ES
dc.contributor.author Martínez-Pérez-Cejuela, H. es_ES
dc.contributor.author Catalá-Icardo, Mónica es_ES
dc.contributor.author Simó-Alfonso, E. F. es_ES
dc.contributor.author Lhotská, I. es_ES
dc.contributor.author atínský, D. es_ES
dc.contributor.author Herrero-Martínez, J. M. es_ES
dc.date.accessioned 2022-11-24T19:03:27Z
dc.date.available 2022-11-24T19:03:27Z
dc.date.issued 2022-03 es_ES
dc.identifier.issn 0026-3672 es_ES
dc.identifier.uri http://hdl.handle.net/10251/190171
dc.description.abstract [EN] A novel coating based on hybrid monolith with metal-organic framework (MOF) onto conventional Teflon-coated magnetic stir bars was developed. For this purpose, the external surface of the Teflon stir bar was firstly vinylized in order to immobilize a glycidyl methacrylate (GMA)-based polymer onto the magnet. Then, an amino-modified MOF of type MIL-101 (NH2-MIL-101(Al)) was covalently attached to the GMA-based monolith. After the synthesis process, several parameters affecting extraction of target estrogens by stir bar sorptive extraction (SBSE) including pH, ionic strength, extraction time, stirring rate, desorption solvent, and desorption time were also investigated. The resulting hybrid monolith was evaluated as SBSE sorbent for extraction of three estrogens (estrone, 17 beta-estradiol, estriol) and synthetic 17 beta-ethinylestradiol from water and human urine samples followed by HPLC with fluorescence detection (excitation and emission wavelengths, 280 and 310 nm, respectively). Under the optimal experimental conditions, the analytical figures of the method were established, achieving satisfactory limits of detection in the range of 0.015-0.58 mu g L-1, recovery results ranging from 70 to 95% with RSD less than 6%, and precision values (intra- and inter-extraction units) below 6%. es_ES
dc.description.sponsorship H. Martinez-Perez-Cejuela thanks the MSIU for a PhD FPU grant (ref. FPU18/02179). S. Z., I. L., and D. S. acknowledge the financial support of the Charles University (Project SVV 260 548), Charles University Grant Agency (Project GAUK No. 1070120), and EFSA-CDN project (no. CZ.02.1.01/0.0/0.0/16_019/0000841) cofunded by ERDF. This article is based upon work from the Sample Preparation Task Force and Network, supported by the Division of Analytical Chemistry of the European Chemical Society. es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Microchimica Acta es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Estrogens es_ES
dc.subject Hybrid monolith es_ES
dc.subject Metal-organic framework es_ES
dc.subject PTFE magnet es_ES
dc.subject Stir bar es_ES
dc.subject Extraction es_ES
dc.subject HPLC-fluorescence detection es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Development of hybrid monoliths incorporating metal¿organic frameworks for stir bar sorptive extraction coupled with liquid chromatography for determination of estrogen endocrine disruptors in water and human urine samples es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s00604-022-05208-6 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FEDER//CZ.02.1.01%2F0.0%2F0.0%2F16_019%2F0000841/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MCIU//FPU18%2F02179/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CU//1070120/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CU//SVV 260 548/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Gandia - Escola Politècnica Superior de Gandia es_ES
dc.description.bibliographicCitation Zatrochová, S.; Martínez-Pérez-Cejuela, H.; Catalá-Icardo, M.; Simó-Alfonso, EF.; Lhotská, I.; Atínský, D.; Herrero-Martínez, JM. (2022). Development of hybrid monoliths incorporating metal¿organic frameworks for stir bar sorptive extraction coupled with liquid chromatography for determination of estrogen endocrine disruptors in water and human urine samples. Microchimica Acta. 189(3):1-10. https://doi.org/10.1007/s00604-022-05208-6 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s00604-022-05208-6 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 189 es_ES
dc.description.issue 3 es_ES
dc.identifier.pmid 35132465 es_ES
dc.identifier.pmcid PMC8821068 es_ES
dc.relation.pasarela S\465821 es_ES
dc.contributor.funder Charles University in Prague es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
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dc.subject.ods 03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edades es_ES
dc.subject.ods 06.- Garantizar la disponibilidad y la gestión sostenible del agua y el saneamiento para todos es_ES


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