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Rational Design of Simple Organocatalysts for the HSiCl3 Enantioselective Reduction of (E)-N-(1-Phenylethylidene)aniline

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Rational Design of Simple Organocatalysts for the HSiCl3 Enantioselective Reduction of (E)-N-(1-Phenylethylidene)aniline

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Maciá, M.; Porcar, R.; Martí-Centelles, V.; García-Verdugo, E.; Burguete, MI.; Luis, SV. (2021). Rational Design of Simple Organocatalysts for the HSiCl3 Enantioselective Reduction of (E)-N-(1-Phenylethylidene)aniline. Molecules. 26(22):1-19. https://doi.org/10.3390/molecules26226963

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/192745

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Title: Rational Design of Simple Organocatalysts for the HSiCl3 Enantioselective Reduction of (E)-N-(1-Phenylethylidene)aniline
Author: Maciá, María Porcar, Raúl Martí-Centelles, Vicente García-Verdugo, Eduardo Burguete, Maria Isabel Luis, Santiago V.
Issued date:
Abstract:
[EN] Prolinamides are well-known organocatalysts for the HSiCl3 reduction of imines; however, custom design of catalysts is based on trial-and-error experiments. In this work, we have used a combination of computational ...[+]
Subjects: Organocatalysis , Asymmetric catalysis , Trichlorosilane , Imine reduction , Mechanistic studies
Copyrigths: Reconocimiento (by)
Source:
Molecules. (eissn: 1420-3049 )
DOI: 10.3390/molecules26226963
Publisher:
MDPI AG
Publisher version: https://doi.org/10.3390/molecules26226963
Project ID:
info:eu-repo/grantAgreement/GV INNOV.UNI.CIENCIA//CIDEGENT%2F2020%2F031//CAJAS ORGANICAS COMO CONTENEDORES PARA LIBERACION DIRIGIDA DE FARMACOS EN TERAPIA CONTRA EL CANCER/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098233-B-C22/ES/NUEVOS PROCESOS MULTI-CATALITICOS VERDES BASADOS EN LA TECNOLOGIA DE LOS LIQUIDOS IONICOS: DESDE LAS MATERIAS PRIMAS SENCILLAS HASTA LOS QUIMICOS CON VALOR AÑADIDO/
info:eu-repo/grantAgreement/GVA//AICO%2F2021%2F139/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2016%2F071//Una aproximación a la sostenibilidad basa en sistemes mult-catalíticos inspirados en el modelo celuar-syncell/
info:eu-repo/grantAgreement/UJI//UJI-B2019-40/
Thanks:
This research was funded by Generalitat Valenciana, grant number PROMETEO/2016/071 and AICO/2021/139, Pla de Promocio de la Investigacio de la Universitat Jaume I, grant number UJI-B2019-40 and Ministerio de Ciencia, ...[+]
Type: Artículo

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