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Active and Regioselective Ru Single-Site Heterogeneous Catalystsfor Alpha-Olefin Hydroformylation

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Active and Regioselective Ru Single-Site Heterogeneous Catalystsfor Alpha-Olefin Hydroformylation

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dc.contributor.author Escobar-Bedia, Francisco Javier es_ES
dc.contributor.author Lopez-Haro, Miguel es_ES
dc.contributor.author Calvino, Jose Juan es_ES
dc.contributor.author Martin-Diaconescu, Vlad es_ES
dc.contributor.author Simonelli, Laura es_ES
dc.contributor.author Pérez-Dieste, Virginia es_ES
dc.contributor.author Sabater Picot, Mª José es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2023-05-22T18:02:21Z
dc.date.available 2023-05-22T18:02:21Z
dc.date.issued 2022-04-01 es_ES
dc.identifier.issn 2155-5435 es_ES
dc.identifier.uri http://hdl.handle.net/10251/193507
dc.description.abstract [EN] A heterogeneous ruthenium catalyst consisting ofisolated single atoms and disordered clusters stabilized in a N-doped carbon matrix has been synthesized with very good activityand remarkable regioselectivity in the hydroformylation of 1-hexene. The role of the nitrogen heteroatoms has been probedessential to increase the catalyst stability and activity, enabling thestabilization of Ru(II)-N sites according to X-ray photoelectronspectroscopy (XPS) and XANES. Intrinsic size-dependent activityof Ru species of different atomicity has been extracted, correlatingthe observed reaction rate and the particle size distributiondetermined by means of aberration-corrected high-angle annulardark-field scanning transmission electron microscopy, permittingthe identification of single-atom sites as the most active ones. This catalyst appears as a promising alternative with respect to itsheterogeneous counterparts, paving the way for designing improved Ru heterogeneous catalysts. es_ES
dc.description.sponsorship The research leading to these results has received funding from the Spanish Ministry of Science, Innovation and Universities, through the "Severo Ochoa" Excellence Programme (SEV2016-0683) and RTI2018-099668-B-C21 and PGC2018101247-B-100 "Programa Estatal de Generacion de Conocimiento". P.C acknowledges the financial support from the "Generalitat Valenciana" through the project AICO/2020/205. HR-HAADF-STEM measurements were performed at the DME-UCA node of ELECMI ICTS with financial support from FEDER/MINECO (MAT2017-87579-R and PID2019110018GA-I00); XAS experiments were performed at the BL22-CLAESS beamline at the ALBA Synchrotron with the collaboration of ALBA staff as part of projects 2019093692 and 2020024106. XPS experiments were performed at the BL24CIRCE beamline at the ALBA Synchrotron with the collaboration of ALBA staff. J.E.B acknowledges the Polytechnical University of Valencia for the economic support through the grant of an FPI scholarship associated with the PAID programme "Programa de Ayudas de Investigacion y Desarrollo". es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS Catalysis es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ruthenium es_ES
dc.subject Hydroformylation es_ES
dc.subject Single site es_ES
dc.subject 1-hexene es_ES
dc.subject Ruthenium cluster es_ES
dc.subject Regioselectivity es_ES
dc.title Active and Regioselective Ru Single-Site Heterogeneous Catalystsfor Alpha-Olefin Hydroformylation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acscatal.1c05737 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-87579-R/ES/FASES 2D ULTRAFINAS SOBRE OXIDOS CON MORFOLOGIA CONTROLADA: PLATAFORMA DE NANOCATALIZADORES MULTICOMPONENTE CON APLICACIONES EN PROTECCION DEL MEDIO AMBIENTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2020%2F205/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-101247-B-I00/ES/RECONOCIMIENTO MOLECULAR EN CATALIZADORES SOLIDOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-110018GA-I00/ES/HACIA CATALIZADORES HOMO Y HETERO DIATOMICOS DE AU-PD SOPORTADOS SOBRE OXIDOS: SINTEIS, CATACTERIZACION ATOMICA Y ACTIVIDAD EN LA REACCION DE OXIDACION SELECTIVA DE ALCOHOLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Escobar-Bedia, FJ.; Lopez-Haro, M.; Calvino, JJ.; Martin-Diaconescu, V.; Simonelli, L.; Pérez-Dieste, V.; Sabater Picot, MJ.... (2022). Active and Regioselective Ru Single-Site Heterogeneous Catalystsfor Alpha-Olefin Hydroformylation. ACS Catalysis. 12(7):4182-4193. https://doi.org/10.1021/acscatal.1c05737 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acscatal.1c05737 es_ES
dc.description.upvformatpinicio 4182 es_ES
dc.description.upvformatpfin 4193 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 7 es_ES
dc.relation.pasarela S\490433 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Universitat Politècnica de València es_ES


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