dc.contributor.author |
Cerezo-Navarrete, Christian
|
es_ES |
dc.contributor.author |
Mustieles Marin, Irene
|
es_ES |
dc.contributor.author |
García-Miquel, Héctor
|
es_ES |
dc.contributor.author |
Corma Canós, Avelino
|
es_ES |
dc.contributor.author |
Chaudret, Bruno
|
es_ES |
dc.contributor.author |
Martínez-Prieto, Luis Miguel
|
es_ES |
dc.date.accessioned |
2023-05-22T18:02:38Z |
|
dc.date.available |
2023-05-22T18:02:38Z |
|
dc.date.issued |
2022-07-15 |
es_ES |
dc.identifier.issn |
2155-5435 |
es_ES |
dc.identifier.uri |
http://hdl.handle.net/10251/193517 |
|
dc.description.abstract |
[EN] The development of energetically efficient processes for the aqueous reduction of biomass-derived compounds into chemicals is key for the optimal transformation of biomass. Herein we report an early example of the reduction of biomass-derived oxygenated compounds in water by magnetically induced catalysis. Non-coated and carbon-coated core-shell FeCo@Ni magnetic nanoparticles were used as the heating agent and the catalyst simultaneously. In this way it was possible to control the product distribution by adjusting the field amplitude applied during the magnetic catalysis, opening a precedent for this type of catalysis. Finally, the encapsulation of the magnetic nanoparticles in carbon (FeCo@Ni@C) strongly improved the stability of the magnetic catalyst in solution, making its reuse possible up to at least eight times in dioxane and four times in water. |
es_ES |
dc.description.sponsorship |
The authors thank the Agencia Estatal de Investigacion (AEI), the Ministerio de Ciencia e Innovacion (MCIN), and the "Ramon y Cajal" program (RYC2020-030031-I) for financial support. The authors also acknowledge an ERC Advanced Grant (MONACAT 2015-694159). C.C.-N. gratefully thanks Generalitat Valenciana for a predoctoral fellowship (GVA: ACIF/2019/076). |
es_ES |
dc.language |
Inglés |
es_ES |
dc.publisher |
American Chemical Society |
es_ES |
dc.relation.ispartof |
ACS Catalysis |
es_ES |
dc.rights |
Reserva de todos los derechos |
es_ES |
dc.subject |
Magnetic nanoparticles |
es_ES |
dc.subject |
Core-shell nanoparticles |
es_ES |
dc.subject |
Magnetically induced catalysis |
es_ES |
dc.subject |
Hydrogenation reactions |
es_ES |
dc.subject |
Biomass-derived compounds |
es_ES |
dc.subject.classification |
TECNOLOGIA ELECTRONICA |
es_ES |
dc.title |
Magnetically Induced Catalytic Reduction of Biomass-Derived
Oxygenated Compounds in Water |
es_ES |
dc.type |
Artículo |
es_ES |
dc.identifier.doi |
10.1021/acscatal.2c01696 |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/ERC//MONACAT 2015-694159/ |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/GVA//ACIF%2F2019%2F076/ |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/MICINN//RYC2020-030031-I/ |
es_ES |
dc.rights.accessRights |
Abierto |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros de Telecomunicación - Escola Tècnica Superior d'Enginyers de Telecomunicació |
es_ES |
dc.description.bibliographicCitation |
Cerezo-Navarrete, C.; Mustieles Marin, I.; García-Miquel, H.; Corma Canós, A.; Chaudret, B.; Martínez-Prieto, LM. (2022). Magnetically Induced Catalytic Reduction of Biomass-Derived
Oxygenated Compounds in Water. ACS Catalysis. 12(14):8462-8475. https://doi.org/10.1021/acscatal.2c01696 |
es_ES |
dc.description.accrualMethod |
S |
es_ES |
dc.relation.publisherversion |
https://doi.org/10.1021/acscatal.2c01696 |
es_ES |
dc.description.upvformatpinicio |
8462 |
es_ES |
dc.description.upvformatpfin |
8475 |
es_ES |
dc.type.version |
info:eu-repo/semantics/publishedVersion |
es_ES |
dc.description.volume |
12 |
es_ES |
dc.description.issue |
14 |
es_ES |
dc.relation.pasarela |
S\475879 |
es_ES |
dc.contributor.funder |
Generalitat Valenciana |
es_ES |
dc.contributor.funder |
European Research Council |
es_ES |
dc.contributor.funder |
Ministerio de Ciencia e Innovación |
es_ES |