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IDM-1: A Zeolite with Intersecting Medium and Extra-Large Pores Built as an Expansion of Zeolite MFI

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IDM-1: A Zeolite with Intersecting Medium and Extra-Large Pores Built as an Expansion of Zeolite MFI

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dc.contributor.author Villaescusa Alonso, Luis Angel es_ES
dc.contributor.author Li, Jian es_ES
dc.contributor.author Gao, Zihao es_ES
dc.contributor.author Sun, Junliang es_ES
dc.contributor.author Camblor, Miguel A. es_ES
dc.date.accessioned 2023-05-23T18:01:48Z
dc.date.available 2023-05-23T18:01:48Z
dc.date.issued 2020-07-06 es_ES
dc.identifier.issn 1433-7851 es_ES
dc.identifier.uri http://hdl.handle.net/10251/193535
dc.description This is the peer reviewed version of the following article: Villaescusa, L. A., Li, J., Gao, Z., Sun, J., & Camblor, M. A. (2020). IDM¿1: A Zeolite with Intersecting Medium and Extra¿Large Pores Built as an Expansion of Zeolite MFI. Angewandte Chemie International Edition, 59(28), 11283-11286, which has been published in final form at https://doi.org/10.1002/anie.202001740. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] IDM-1 is a new silica zeolite with an ordered and well-defined framework constructed by alternating pentasil layers and interrupted layers, giving rise to an intersecting system of straight medium pores and undulating extra-large lobed pores. This unique structure was solved by rotation electron diffraction and refined against synchrotron powder X-ray diffraction data. Despite the presence of both Si(OSi)(3)(OH) and Si(OSi)(2)(OH)(2) sites, this new zeolite presents high thermal stability, withstanding calcination even to 1000 degrees C. The location of defects at specific sites of the structure results in alternating hydrophobic SiO2 and hydrophilic SiO(2-x)(OH)(2x) intracrystalline regions. This peculiar combination of intersecting medium and extra-large pores and alternating regions of different chemical character may provide this zeolite with unique catalytic properties. es_ES
dc.description.sponsorship The authors thank funding from the Spanish Ministry of Science, Innovation and Universities, under Projects MAT2015-71117-R (MINECO/FEDER, UE) and RTI2018-101599-B-C22 (MCUI/AEI/FEDER, UE), the National Natural Science Foundation of China (No. 21871009, 21621061, 21527803, 21471009), the Swedish Research Council (VR) and the Knut and Alice Wallenberg Foundation (KAW). L.A.V. also thanks the Generalitat Valenciana (project PROMETEO/2018/024). Synchrotron experiments were performed at beamline BL04 (MSPD) at ALBA Synchrotron with the collaboration of ALBA staff, and special thanks are due to A. Manjon for support in collecting the data and for helpful comments and suggestions. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Extra-large pores es_ES
dc.subject Pentasil es_ES
dc.subject Rotation electron diffraction, Structure solution es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title IDM-1: A Zeolite with Intersecting Medium and Extra-Large Pores Built as an Expansion of Zeolite MFI es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.202001740 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101599-B-C22/ES/DESARROLLO Y APLICACION DE SISTEMAS ANTIMICROBIANOS PARA LA INDUSTRIA ALIMENTARIA BASADOS EN SUPERFICIES FUNCIONALIZADAS Y SISTEMAS DE LIBERACION CONTROLADA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21871009/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71117-R/ES/NUEVAS ARQUITECTURAS HIBRIDAS MEDIANTE ENSAMBLADO CONTROLADO DE NANOMATERIALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21621061/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21527803/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21471009/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F024//Sistemas avanzados de liberación controlada/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Villaescusa Alonso, LA.; Li, J.; Gao, Z.; Sun, J.; Camblor, MA. (2020). IDM-1: A Zeolite with Intersecting Medium and Extra-Large Pores Built as an Expansion of Zeolite MFI. Angewandte Chemie International Edition. 59(28):11283-11286. https://doi.org/10.1002/anie.202001740 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/anie.202001740 es_ES
dc.description.upvformatpinicio 11283 es_ES
dc.description.upvformatpfin 11286 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 59 es_ES
dc.description.issue 28 es_ES
dc.identifier.pmid 32291867 es_ES
dc.relation.pasarela S\439834 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Swedish Research Council es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Knut and Alice Wallenberg Foundation es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder National Natural Science Foundation of China es_ES


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