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dc.contributor.author | Torres-Giner, Sergio | es_ES |
dc.contributor.author | Lagaron, Jose M. | es_ES |
dc.date.accessioned | 2023-06-07T18:01:11Z | |
dc.date.available | 2023-06-07T18:01:11Z | |
dc.date.issued | 2010-10-15 | es_ES |
dc.identifier.issn | 0021-8995 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/193933 | |
dc.description | This is the peer reviewed version of the following article: Torres-Giner, S., & Lagaron, J. M. (2010). Zein-based ultrathin fibers containing ceramic nanofillers obtained by electrospinning. I. Morphology and thermal properties. Journal of applied polymer science, 118(2), 778-789., which has been published in final form at 10.1002/app.32180. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | es_ES |
dc.description.abstract | [EN] This work presents the first results on the development and characterization of novel nanobiocomposite fibers prepared by electrospinning of zein/clay mixtures (from 99/1 to 75/25 wt/wt) from ethanol-based solutions. To do so, commercial ceramic materials of different nature, such as organomodified and unmodified mica, kaolinite, montmorillonite, and zeolite were employed and compared. A significant decrease in fiber diameter was observed as the clay fraction increased in the hybrid material. The highest clay contents also produced fibers but with extended beaded regions. All fillers nanodispersed well in the fibers at low loadings but unmodified mica particles were also seen excluded from the fibers, most likely due to excessive size. Surprisingly, the ceramic laminar structures, i.e. the phyllosilicates, were all seen to embed within the ultrathin fibers in what appears as an unreported rolled morphology due to the extensional forces generated by the electrospinning process. Electrospun nanobiocomposite fibers with optimal ceramic nanoparticle contents are currently investigated as an adequate procedure to prepare naturally occurring composite additives, coatings, and interlayers with enhanced performance in terms of mechanical, thermal, barrier, and control release properties for packaging, active packaging, biomedical, and pharmaceutical applications. | es_ES |
dc.description.sponsorship | Contract grant sponsor: MEC; contract grant numbers: MAT2009-14533-C02-01, MAT2006-10261-C03. Contract grant sponsor: EU FP6, NEWBONE | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Journal of Applied Polymer Science | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Zein | es_ES |
dc.subject | Nanocomposites | es_ES |
dc.subject | Electrospinning | es_ES |
dc.subject | Renewable polymers | es_ES |
dc.title | Zein-based ultrathin fibers containing ceramic nanofillers obtained by electrospinning. I. Morphology and thermal properties | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/app.32180 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MEC//MAT2006-10261-C03-01/ES/DESARROLLO Y OPTIMIZACI?N DE NUEVOS NANOBIOCOMPUESTOS CON PROPIEDADES BARRERA Y T?RMICAS MEJORADAS PARA SU APLICACI?N EN ENVASADO DE ALIMENTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2009-14533-C02-01/ES/Desarrollo Y Caracterizacion De Nanoaditivos Reforzantes, Antimicrobianos Y Bioactivos Y De Sus Nanocompuestos Con Biopoliesteres De Interes En Aplicaciones De Encapsulado Y Envases Alimentarios/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament | es_ES |
dc.description.bibliographicCitation | Torres-Giner, S.; Lagaron, JM. (2010). Zein-based ultrathin fibers containing ceramic nanofillers obtained by electrospinning. I. Morphology and thermal properties. Journal of Applied Polymer Science. 118(2):778-789. https://doi.org/10.1002/app.32180 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/app.32180 | es_ES |
dc.description.upvformatpinicio | 778 | es_ES |
dc.description.upvformatpfin | 789 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 118 | es_ES |
dc.description.issue | 2 | es_ES |
dc.relation.pasarela | S\427575 | es_ES |
dc.contributor.funder | Ministerio de Educación y Ciencia | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |