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Phosphorus-Rich Ruthenium Phosphide Embedded on a 3D Porous Dual-Doped Graphitic Carbon for Hydrogen Evolution Reaction

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Phosphorus-Rich Ruthenium Phosphide Embedded on a 3D Porous Dual-Doped Graphitic Carbon for Hydrogen Evolution Reaction

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dc.contributor.author Anouar, Aicha es_ES
dc.contributor.author Antonio Doménech-Carbó es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2023-06-19T18:01:05Z
dc.date.available 2023-06-19T18:01:05Z
dc.date.issued 2022-10 es_ES
dc.identifier.uri http://hdl.handle.net/10251/194383
dc.description.abstract [EN] Metal phosphides have recently emerged as promising electrocatalysts for hydrogen evolution reaction (HER). Herein, we report the synthesis of ruthenium diphosphide embedded on a dual-doped graphitic carbon by pyrolyzing chitosan beads impregnated with ruthenium chloride and phosphorus pentoxide. The as-synthesized RuP2@N-P-C displays a good electrocatalytic activity in acidic, neutral and alkaline media. We show that the HER activity of the electrocatalyst can be tuned by varying the concentration of Li+ cations. Co-diffusion effects on H+ exerted by Li+ on HER in the porous carbon matrix have been observed. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Science and Innovation (PDI2022- 126071OB-C21 and Severo Ochoa) and the Generalitat Valenciana (Prometeo 2021-038) are gratefully acknowledged. A.A. thanks assistance from Erasmus+ for partial support of her stay at Valencia. The European Commission is acknowledged for partial funding through the ECO2Fuel project. UEMF is acknowledged for financial support. A.A. thanks UEMF and UPV for an Erasmus+ 2019-1-ES01-KA107-062073 Scholarship. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Nanomaterials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ruthenium electrocatalysts es_ES
dc.subject Metal phosphides es_ES
dc.subject Ruthenium diphosphide es_ES
dc.subject Dual-doped graphitic carbon es_ES
dc.subject Hydrogen evolution reaction es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Phosphorus-Rich Ruthenium Phosphide Embedded on a 3D Porous Dual-Doped Graphitic Carbon for Hydrogen Evolution Reaction es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/nano12203597 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/101037389/EU es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2021%2F038//HETEROGENEOUS (ELECTRO-/PHOTO-)CATALYSTS FOR HYDROGEN TECHNOLOGY Cat4Hytec/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//2019-1-ES01-KA107-062073/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//PDI2022-126071OB-C21/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Anouar, A.; Antonio Doménech-Carbó; García Gómez, H. (2022). Phosphorus-Rich Ruthenium Phosphide Embedded on a 3D Porous Dual-Doped Graphitic Carbon for Hydrogen Evolution Reaction. Nanomaterials. 12(20):1-15. https://doi.org/10.3390/nano12203597 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/nano12203597 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 15 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 20 es_ES
dc.identifier.eissn 2079-4991 es_ES
dc.identifier.pmid 36296788 es_ES
dc.identifier.pmcid PMC9606981 es_ES
dc.relation.pasarela S\486864 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD es_ES


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