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Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applications

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Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applications

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dc.contributor.author Bouich, Amal es_ES
dc.contributor.author Marí-Guaita, Julia es_ES
dc.contributor.author Baig, Faisal es_ES
dc.contributor.author Khattak, Yousaf Hameed es_ES
dc.contributor.author Marí, B. es_ES
dc.contributor.author Palacios, Pablo es_ES
dc.date.accessioned 2023-06-22T18:02:46Z
dc.date.available 2023-06-22T18:02:46Z
dc.date.issued 2022-09 es_ES
dc.identifier.uri http://hdl.handle.net/10251/194500
dc.description.abstract [EN] Presently, we inquire about the organic/inorganic cation effect on different properties based on structure, morphology, and steadiness in preparing a one-step solution of APbI(3) thin films, where A = MA, FA, Cs, using spin coating. This study was conducted to understand those properties well by incorporating device modeling using SCAPS-1D software and to upgrade their chemical composition. X-ray diffraction (XRD) was used to analyze the crystal structures. Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM) were conducted to characterize the surface morphology; photoluminescence, Transmission Electron Microscopy (TEM), and a UV-Visible spectrometer helped us to study the optical properties. The (110) plane is where we found the perovskite's crystalline structure. According to the XRD results and by changing the type of cation, we influence stabilization and the growth of the APbI(3) absorber layer. Hither, a homogenous, smooth-surfaced, pinhole-free perovskite film and large grain size are results from the cesium cation. For the different cations, the band gap's range, revealed by the optical analysis, is from 1.4 to 1.8 eV. Moreover, the stability of CsPbI3 remains excellent for two weeks and in a similar to 60% humid environment. Based on the UV-Visible spectrometer and photoluminescence characterization, a numerical analysis for fabricated samples was also performed for stability analysis by modeling standard solar-cell structures HTL/ APbI(3) / ETL. Modeling findings are in good agreement with experimental results that CsPbI3 is more stable, showing a loss % in PCE of 14.28%, which is smaller in comparison to FAPbI(3) (44.46%) and MAPbI(3) (20.24%). es_ES
dc.description.sponsorship The author Amal Bouich postdoctoral researcher acknowledges Margarita Salas Fellowship (MCIN/AEI/10.13039/501100011033) for funding support. This work was supported by EU under Project PID2019-107137RB-C21 and by ERDF under the funding ¿A way of making Europe¿. This work was supported by the Ministerio de Ciencia e Innvación through the project BESTMAT (PID2019-107137RB-C21) and (PID2019-107137RB-C22). We would like to thank Ministerio de Economia y Competitividad (Spain) for supporting this work and Margarita Salas Fellowship. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Nanomaterials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Thin films es_ES
dc.subject APbI3 es_ES
dc.subject Organic/inorganic perovskite es_ES
dc.subject Optical properties es_ES
dc.subject Stability es_ES
dc.subject SCAPS-1D es_ES
dc.subject Numerical analysis es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/nano12173027 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107137RB-C21/ES/MEJORANDO LA PRODUCCION DE ENERGIA SOLAR CON PEROVSKITAS INORGANICAS.SINTESIS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNIVERSIDAD POLITECNICA DE VALENCIA//MS%2F27//AYUDA MARGARITA SALAS DE BOUICH, AMAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107137RB-C22/ES/MEJORANDO LA PRODUCCION DE ENERGIA SOLAR CON MATERIALES SEMICONDUCTORES BASADOS EN PEROVSKITAS INORGANICAS-CALCULOS CUANTICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny es_ES
dc.description.bibliographicCitation Bouich, A.; Marí-Guaita, J.; Baig, F.; Khattak, YH.; Marí, B.; Palacios, P. (2022). Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applications. Nanomaterials. 12(17):1-19. https://doi.org/10.3390/nano12173027 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/nano12173027 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 19 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 17 es_ES
dc.identifier.eissn 2079-4991 es_ES
dc.identifier.pmid 36080064 es_ES
dc.identifier.pmcid PMC9457585 es_ES
dc.relation.pasarela S\471596 es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder UNIVERSIDAD POLITECNICA DE VALENCIA es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
upv.costeAPC 724,45 es_ES


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