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dc.contributor.author | Carceller-Carceller, Jose Miguel | es_ES |
dc.contributor.author | Arias-Carrascal, Karen Sulay | es_ES |
dc.contributor.author | Climent Olmedo, María José | es_ES |
dc.contributor.author | Iborra Chornet, Sara | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2024-01-02T19:02:40Z | |
dc.date.available | 2024-01-02T19:02:40Z | |
dc.date.issued | 2022-09-16 | es_ES |
dc.identifier.issn | 2095-5138 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/201341 | |
dc.description.abstract | [EN] Amino transaminases (ATAs) have been supported on a 2D ITQ-2 zeolite through electrostatic interactions, resulting in a highly stable active biocatalyst to obtain a variety of valuable chiral amines starting from prochiral ketones derived from biomass. We have extended the biocatalyst applications by designing a chemo-enzymatic process that allows, as the first step, prochiral ketones to be obtained from biomass-derived compounds through an aldol condensation-reduction step using a bifunctional metal/base catalyst. The prochiral ketone is subsequently converted into the chiral amine using the immobilized ATA. We show that it is feasible to couple both steps in a semi-continuous process to produce industrially relevant chiral amines with yields of >95% and similar to 100% enantiomer excess. | es_ES |
dc.description.sponsorship | This work was supported by the SpanishGovernment through the `Severo Ochoa Program' (SEV-2016-0683) and the PGC2018097 277-B-100 (MCIU/AEI/FEDER, UE) Project. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Oxford University Press | es_ES |
dc.relation.ispartof | National Science Review | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Amino transaminase | es_ES |
dc.subject | ITQ-2 zeolite | es_ES |
dc.subject | Chemo-enzymatic process | es_ES |
dc.subject | Biomass | es_ES |
dc.subject | Semi-continuous process | es_ES |
dc.subject | Pd,MgO | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Enzymatic and chemo-enzymatic strategies to produce highly valuable chiral amines from biomass with omega-transaminases on 2D zeolites | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1093/nsr/nwac135 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097277-B-I00/ES/MEJORA DEL CONCEPTO DE BIORREFINERIA MEDIANTE IMPLEMENTACION DE NUEVOS PROCESOS CATALITICOS CON CATALIZADORES SOLIDOS DE METALES NO NOBLES PARA LA PRODUCCION DE BIOCOMPUESTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Carceller-Carceller, JM.; Arias-Carrascal, KS.; Climent Olmedo, MJ.; Iborra Chornet, S.; Corma Canós, A. (2022). Enzymatic and chemo-enzymatic strategies to produce highly valuable chiral amines from biomass with omega-transaminases on 2D zeolites. National Science Review. 9(9):1-9. https://doi.org/10.1093/nsr/nwac135 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1093/nsr/nwac135 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 9 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 9 | es_ES |
dc.description.issue | 9 | es_ES |
dc.identifier.pmid | 36131886 | es_ES |
dc.identifier.pmcid | PMC9479500 | es_ES |
dc.relation.pasarela | S\481374 | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |
dc.contributor.funder | MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD | es_ES |
dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |