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dc.contributor.author | Velty, Alexandra![]() |
es_ES |
dc.contributor.author | Iborra Chornet, Sara![]() |
es_ES |
dc.contributor.author | Corma Canós, Avelino![]() |
es_ES |
dc.date.accessioned | 2024-04-11T06:14:22Z | |
dc.date.available | 2024-04-11T06:14:22Z | |
dc.date.issued | 2022-04 | es_ES |
dc.identifier.issn | 1864-5631 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/203281 | |
dc.description.abstract | [EN] 5-hydroxymethylfurfural (HMF) is one of the most valuable biomass platform molecules, enabling the construction of a plethora of high value-added furanic compounds. In particular, in the last decade, HMF has been considered as a starting material for designing biobased surfactants, not only because of its renewability and carbon footprint, but also because of its enhanced biodegradability. This Review presents recent examples of the different approaches to link the hydrophilic and lipophilic moieties into the hydrophobic furan (and tetrahydrofuran) ring, giving a variety of biobased surfactants that have been classified here according to the charge of the head polar group. Moreover, strategies for the synthesis of different non-furanic structures surfactant molecules (such as levulinic acid, cyclopentanols, and aromatics) derived from HMF are described. The new HMF-based amphiphilic molecules presented here cover a wide range of hydrophilic-lipophilic balance values and have suitable surfactant properties such as surface tension activity and critical micelle concentration, to be an important alternative for the replacement of non-sustainable surfactants. | es_ES |
dc.description.sponsorship | This work has been supported by the Spanish government through the "Severo Ochoa Program" (SEV-2016-0683) and the PGC2018-097277-B-100 (MCIU/AEI/FEDER, UE) project. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | ChemSusChem | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Surfactants | es_ES |
dc.subject | HMF | es_ES |
dc.subject | Levulinic acid | es_ES |
dc.subject | 3-hydroxycyclopentanol | es_ES |
dc.subject | Aromatics | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Synthetic Routes for Designing Furanic and Non Furanic Biobased Surfactants from 5-Hydroxymethylfurfural | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/cssc.202200181 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097277-B-I00/ES/MEJORA DEL CONCEPTO DE BIORREFINERIA MEDIANTE IMPLEMENTACION DE NUEVOS PROCESOS CATALITICOS CON CATALIZADORES SOLIDOS DE METALES NO NOBLES PARA LA PRODUCCION DE BIOCOMPUESTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Velty, A.; Iborra Chornet, S.; Corma Canós, A. (2022). Synthetic Routes for Designing Furanic and Non Furanic Biobased Surfactants from 5-Hydroxymethylfurfural. ChemSusChem. 15(13). https://doi.org/10.1002/cssc.202200181 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/cssc.202200181 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 15 | es_ES |
dc.description.issue | 13 | es_ES |
dc.identifier.pmid | 35325511 | es_ES |
dc.identifier.pmcid | PMC9401603 | es_ES |
dc.relation.pasarela | S\485196 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |