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dc.contributor.author | Herrera-Luna, Jorge Carlos | es_ES |
dc.contributor.author | Pérez-Aguilar, María Carmen | es_ES |
dc.contributor.author | Gerken, Leon | es_ES |
dc.contributor.author | Garcia Mancheño, Olga | es_ES |
dc.contributor.author | Jiménez Molero, María Consuelo | es_ES |
dc.contributor.author | Pérez-Ruiz, Raúl | es_ES |
dc.date.accessioned | 2024-04-11T11:40:50Z | |
dc.date.available | 2024-04-11T11:40:50Z | |
dc.date.issued | 2023-01-27 | es_ES |
dc.identifier.issn | 0947-6539 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/203409 | |
dc.description.abstract | [EN] A novel visible light promoted formation of CAryl-S bonds through electron donor-acceptor (EDA) complexes of alkylamines with 5- and 6-membered (hetero)arene halides is presented. This represents the first EDA-based thiolation method not relying on pi-pi or a thiolate-anion-pi interactions and provides a facile access to heteroarene radicals, which can be suitably trapped by disulfide derivatives to form the corresponding versatile arylsulfides. Mechanistic investigations on the aspects of the whole process were conducted by spectroscopic measurements, demonstrating the hypothesized EDA complex formation. Moreover, the strength of this method has been proven by a gram-scale synthesis of thiolated products and the late-stage derivatization of an anticoagulant drug. | es_ES |
dc.description.sponsorship | Financial support from the Generalitat Valenciana (project CIDEGENT/2018/044), the Spanish Government (project PID2019-105391GB-C22 and fellowship BES-2017-080215 funded by MCIN/AEI/10.13039/501100011033) is gratefully acknowledged. The Deutsche Forschungsgemeinschaft (DFG, project GA1594/6-2) and the European Research Council (ERC-CG 724695) are also acknowledged for generous support. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Chemistry - A European Journal | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | EDA complex | es_ES |
dc.subject | Heteroarene thiolation | es_ES |
dc.subject | Single-electron transfer | es_ES |
dc.subject | Sustainability | es_ES |
dc.subject | Visible-light | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Effective Formation of New C(sp2)-S Bonds via Photoactivation of Alkylamine-based Electron Donor-Acceptor Complexes | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/chem.202203353 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105391GB-C22/ES/DESARROLLO DE NUEVOS SISTEMAS DE CONVERSION BIFOTONICA A MAYOR FRECUENCIA BASADOS EN ANIQUILACION TRIPLETE-TRIPLETE PARA FOTOCATALISIS REDOX CON LUZ VISIBLE/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/724695/EU | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//CIDEGENT%2F2018%2F044//PHOTON UPCONVERSION REDOX CATALYSIS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/DFG//GA1594%2F6-2/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//BES-2017-080215//AYUDA PARA CONTRATOS PREDOCTORALES PARA LA FORMACION DE DOCTORES 2017-HERRERA LUNA. PROYECTO: CONTROL SUPRAMOLECULAR DE LA FOTORREACTIVIDAD EN MEDIOS MICROHETEROGENOS BASADOS EN AMINOACIDOS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Herrera-Luna, JC.; Pérez-Aguilar, MC.; Gerken, L.; Garcia Mancheño, O.; Jiménez Molero, MC.; Pérez-Ruiz, R. (2023). Effective Formation of New C(sp2)-S Bonds via Photoactivation of Alkylamine-based Electron Donor-Acceptor Complexes. Chemistry - A European Journal. 29(6). https://doi.org/10.1002/chem.202203353 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/chem.202203353 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 29 | es_ES |
dc.description.issue | 6 | es_ES |
dc.identifier.pmid | 36314234 | es_ES |
dc.identifier.pmcid | PMC10107790 | es_ES |
dc.relation.pasarela | S\475657 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | GENERALITAT VALENCIANA | es_ES |
dc.contributor.funder | Deutsche Forschungsgemeinschaft | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |