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Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion

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Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion

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dc.contributor.author Lorente, Alejandro es_ES
dc.contributor.author Ochoa, Andres es_ES
dc.contributor.author Rodriguez-Lavado, Julio es_ES
dc.contributor.author Rodríguez-Nuévalos, Silvia es_ES
dc.contributor.author Jaque, Pablo es_ES
dc.contributor.author Gil, Salvador es_ES
dc.contributor.author Sáez, José A. es_ES
dc.contributor.author Costero, Ana M. es_ES
dc.date.accessioned 2024-05-28T18:18:02Z
dc.date.available 2024-05-28T18:18:02Z
dc.date.issued 2023-01-10 es_ES
dc.identifier.uri http://hdl.handle.net/10251/204474
dc.description.abstract [EN] A new selective fluorogenic chemosensor for Hg2+, which combines a calixarene derivative with a BODIPY core as a fluorescent reporter, is described. The remarkable change in its fluorogenic properties in DMSO and CHCl3 has been analyzed. A study of its spectral properties on dilution, along with molecular modeling studies, allowed us to explain that this behavior involves the formation of a J-dimer, as well as how the sensing mechanism of Hg2+ proceeds. es_ES
dc.description.sponsorship We gratefully acknowledge financial support from Fondecyt Postdoctoral Grants 3170264 and 3180041. PJ acknowledges Fondecyt project no 1181914. Grant RTI2018-100910-B-C42 was funded by MCIN/AEI/10.13039/501100011033 and by "ERDF -A way of making Europe". SCSIE (Universitat de Vale`ncia) is gratefully acknowledged for all the equipment employed. NMR was registered at the U26 facility of ICTS "NANBIOSIS" at the Universitat of Vale`ncia. Funding was also received through the Einstein Research Unit "Climate and Water under Change" from the Einstein Foundation Berlin and Berlin University Alliance (Grant ERU-2020-609). We also want to thank Natxo M. Hermoso (www.natxohermoso.com) for helping us with all the photography in this work. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS Omega es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Fluorescence es_ES
dc.subject Dyes es_ES
dc.subject Derivatives es_ES
dc.subject Readout es_ES
dc.subject Metals es_ES
dc.subject PH es_ES
dc.title Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acsomega.2c06161 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-100910-B-C42/ES/MATERIALES INTELIGENTES PARA LA DETECCION DE DROGAS DE ABUSO Y BIOMARCADORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FEDER//C22%2FERDF/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FONDECYT//1181914/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FONDECYT//3180041/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FONDECYT//3170264/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/BUA//ERU-2020-609/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Lorente, A.; Ochoa, A.; Rodriguez-Lavado, J.; Rodríguez-Nuévalos, S.; Jaque, P.; Gil, S.; Sáez, JA.... (2023). Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion. ACS Omega. 8(1):819-828. https://doi.org/10.1021/acsomega.2c06161 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acsomega.2c06161 es_ES
dc.description.upvformatpinicio 819 es_ES
dc.description.upvformatpfin 828 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 1 es_ES
dc.identifier.eissn 2470-1343 es_ES
dc.relation.pasarela S\519119 es_ES
dc.contributor.funder Einstein Stiftung Berlin es_ES
dc.contributor.funder Universitat de València es_ES
dc.contributor.funder Berlin University Alliance es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Fondo Nacional de Desarrollo Científico y Tecnológico, Chile es_ES


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