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dc.contributor.author | Dhakshinamoorthy, Amarajothi | es_ES |
dc.contributor.author | Navalón Oltra, Sergio | es_ES |
dc.contributor.author | Primo Arnau, Ana Maria | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2024-06-06T18:15:50Z | |
dc.date.available | 2024-06-06T18:15:50Z | |
dc.date.issued | 2024-01-15 | es_ES |
dc.identifier.issn | 1433-7851 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/204761 | |
dc.description.abstract | [EN] Large scale production of green CH3OH obtained from CO2 and green H-2 is a highly wanted process due to the role of CH3OH as H-2/energy carrier and for producing chemicals. Starting with a short summary of the advantages of metal-organic frameworks (MOFs) as catalysts in liquid-phase reactions, the present article highlights the opportunities that MOFs may offer also for some gas-phase reactions, particularly for the selective CO2 hydrogenation to CH3OH. It is commented that there is a temperature compatibility window that combines the thermal stability of some MOFs with the temperature required in the CO2 hydrogenation to CH3OH that frequently ranges from 250 to 300 degrees C. The existing literature in this area is briefly organized according to the role of MOF as providing the active sites or as support of active metal nanoparticles (NPs). Emphasis is made to show how the flexibility in design and synthesis of MOFs can be used to enhance the catalytic activity by adjusting the composition of the nodes and the structure of the linkers. The influence of structural defects and material crystallinity, as well as the role that should play theoretical calculations in models have also been highlighted. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Science and Innovation (CEX-2021-001230-S and PDI2021-0126071-OB-CO21 funded by MCIN/AEI/ 10.13039/501100011033) and Generalitat Valenciana (Prometeo 2021/038 and Advanced Materials programme Graphica MFA/2022/023 with funding from European Union NextGenerationEU PRTR-C17.I1). AD is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU). S.N. thanks the support of Grant PID2021-123856OBI00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe. The METHASOL project receives funding from the European Union Horizon 2020 research and innovation programme under Grant Agreement No 101022649. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
dc.rights | Reconocimiento - No comercial (by-nc) | es_ES |
dc.subject | CO2 Hydrogenation | es_ES |
dc.subject | Gas-Phase Catalysis | es_ES |
dc.subject | Heterogeneous Catalysis | es_ES |
dc.subject | Metal-Organic Frameworks | es_ES |
dc.subject | Methanol Synthesis | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/anie.202311241 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123856OB-I00/ES/FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/101022649/EU/International cooperation for selective conversion of CO2 into METHAnol under SOLar light/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//PID2021-126071OB-C21//APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCIÓN DE COMBUSTIBLES SOLARES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2021%2F038//HETEROGENEOUS (ELECTRO-/PHOTO-)CATALYSTS FOR HYDROGEN TECHNOLOGY Cat4Hytec/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GV INNOV.UNI.CIENCIA//MFA%2F2022%2F023//ELECTRODOS Y FOTOCATALIZADORES A BASE DE GRAFENO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//CEX-2021-001230-S/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//PRTR-C17.I1/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Dhakshinamoorthy, A.; Navalón Oltra, S.; Primo Arnau, AM.; García Gómez, H. (2024). Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks. Angewandte Chemie International Edition. 63(3). https://doi.org/10.1002/anie.202311241 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/anie.202311241 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 63 | es_ES |
dc.description.issue | 3 | es_ES |
dc.identifier.pmid | 37815860 | es_ES |
dc.relation.pasarela | S\511177 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | GENERALITAT VALENCIANA | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |