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Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks

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Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2024-06-06T18:15:50Z
dc.date.available 2024-06-06T18:15:50Z
dc.date.issued 2024-01-15 es_ES
dc.identifier.issn 1433-7851 es_ES
dc.identifier.uri http://hdl.handle.net/10251/204761
dc.description.abstract [EN] Large scale production of green CH3OH obtained from CO2 and green H-2 is a highly wanted process due to the role of CH3OH as H-2/energy carrier and for producing chemicals. Starting with a short summary of the advantages of metal-organic frameworks (MOFs) as catalysts in liquid-phase reactions, the present article highlights the opportunities that MOFs may offer also for some gas-phase reactions, particularly for the selective CO2 hydrogenation to CH3OH. It is commented that there is a temperature compatibility window that combines the thermal stability of some MOFs with the temperature required in the CO2 hydrogenation to CH3OH that frequently ranges from 250 to 300 degrees C. The existing literature in this area is briefly organized according to the role of MOF as providing the active sites or as support of active metal nanoparticles (NPs). Emphasis is made to show how the flexibility in design and synthesis of MOFs can be used to enhance the catalytic activity by adjusting the composition of the nodes and the structure of the linkers. The influence of structural defects and material crystallinity, as well as the role that should play theoretical calculations in models have also been highlighted. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Science and Innovation (CEX-2021-001230-S and PDI2021-0126071-OB-CO21 funded by MCIN/AEI/ 10.13039/501100011033) and Generalitat Valenciana (Prometeo 2021/038 and Advanced Materials programme Graphica MFA/2022/023 with funding from European Union NextGenerationEU PRTR-C17.I1). AD is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU). S.N. thanks the support of Grant PID2021-123856OBI00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe. The METHASOL project receives funding from the European Union Horizon 2020 research and innovation programme under Grant Agreement No 101022649. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject CO2 Hydrogenation es_ES
dc.subject Gas-Phase Catalysis es_ES
dc.subject Heterogeneous Catalysis es_ES
dc.subject Metal-Organic Frameworks es_ES
dc.subject Methanol Synthesis es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.202311241 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123856OB-I00/ES/FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/101022649/EU/International cooperation for selective conversion of CO2 into METHAnol under SOLar light/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//PID2021-126071OB-C21//APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCIÓN DE COMBUSTIBLES SOLARES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//PROMETEO%2F2021%2F038//HETEROGENEOUS (ELECTRO-/PHOTO-)CATALYSTS FOR HYDROGEN TECHNOLOGY Cat4Hytec/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GV INNOV.UNI.CIENCIA//MFA%2F2022%2F023//ELECTRODOS Y FOTOCATALIZADORES A BASE DE GRAFENO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//CEX-2021-001230-S/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//PRTR-C17.I1/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Navalón Oltra, S.; Primo Arnau, AM.; García Gómez, H. (2024). Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks. Angewandte Chemie International Edition. 63(3). https://doi.org/10.1002/anie.202311241 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/anie.202311241 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 63 es_ES
dc.description.issue 3 es_ES
dc.identifier.pmid 37815860 es_ES
dc.relation.pasarela S\511177 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES


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