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On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts

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On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts

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dc.contributor.author Ballesteros Plata, D. es_ES
dc.contributor.author Balestra, G. es_ES
dc.contributor.author Cecilia, J.A. es_ES
dc.contributor.author Barroso Martín, I. es_ES
dc.contributor.author Infantes-Molina, A. es_ES
dc.contributor.author Tabanelli, T. es_ES
dc.contributor.author Cavani, F. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.contributor.author Montaña, M. es_ES
dc.contributor.author Rodríguez Castellón, E. es_ES
dc.date.accessioned 2024-06-06T18:16:03Z
dc.date.available 2024-06-06T18:16:03Z
dc.date.issued 2024-03-01 es_ES
dc.identifier.issn 0920-5861 es_ES
dc.identifier.uri http://hdl.handle.net/10251/204769
dc.description.abstract [EN] MgO-La2O3 catalysts with different Mg/La molar ratio were synthesized by a precipitation method and a subsequent calcination and then characterized by x-ray diffraction, N2 adsorption-desorption isotherms (at-196 degrees C), CO2- and NH3-thermoprogrammed desorption and x-ray photoelectronic spectroscopy. The coexistence of acid and basic sites promoted the selective transformation of ethanol into valuable products. Thus, MgO catalyst promoted the Guerbet reaction obtaining n-butanol as product while the incorporation of La2O3 in the catalytic system improved the ethanol conversion notably, obtaining ethylene as the main product due to a dehydration reaction. The highest ethylene yield was obtained for the catalyst with a Mg/La molar ratio of 1. es_ES
dc.description.sponsorship The funding received for this study from the Spanish Ministry of Science and Innovation, PID2021-126235OB-C31 and PID2021-126235OB-C32 funded by MCIN/AEI/10.13039/501100011033 and FEDER funds, and projects TED2021-130756B-C31 and TED2021-130756B-C32 funded by MCIN/AEI/10.13039/501100011033 and by "ERDF A way of making Europe" by the European Union NextGenerationEU/PRTR, is acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Catalysis Today es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Ethanol es_ES
dc.subject Ethylene es_ES
dc.subject Acetaldehyde es_ES
dc.subject Butanol es_ES
dc.subject Gas-phase es_ES
dc.subject Heterogenous catalyst es_ES
dc.title On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.cattod.2023.114470 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C31/ES/CO2 COMO MATERIA PRIMA EN LA TERMOCATALISIS Y SU TRANSFORMACION EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C32/ES/DESIGN OF SUSTAINABLE MATERIALS FOR N2O Y CO2 CAPTURE AND CATALYTIC VALORIZATION/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//TED2021-130756B-C32/ES/Desarrollo de nuevos catalizadores para reformado en seco y reacciones WGS de biogás y su impacto en la producción sostenible de hidrógeno verde a partir de biogás/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//TED2021-130756B-C31/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Ballesteros Plata, D.; Balestra, G.; Cecilia, J.; Barroso Martín, I.; Infantes-Molina, A.; Tabanelli, T.; Cavani, F.... (2024). On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts. Catalysis Today. 429. https://doi.org/10.1016/j.cattod.2023.114470 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.cattod.2023.114470 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 429 es_ES
dc.relation.pasarela S\513596 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES


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