Octahedral Tantalum Bromide Clusters as Catalysts for Light-Driven Hydrogen Evolution
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https://riunet.upv.es/handle/10251/205210
Cita bibliográfica
Hernandez-Niño, JS.; Guevara, D.; Shamsurin, M.; Benassi, E.; Sokolov, MN.; Feliz Rodriguez, M. (2023). Octahedral Tantalum Bromide Clusters as Catalysts for Light-Driven Hydrogen Evolution. Inorganic Chemistry. 62(46):19060-19069. https://doi.org/10.1021/acs.inorgchem.3c03045
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[EN] Octahedral tantalum clusters are redox-active compounds. [{Ta6Bri12}Bra2(H2O)a4]·4H2O (i = inner; a = apical ligands) cluster results in efficient pre-catalyst for the light-driven H2 production from aqueous protons in homogeneous conditions. The most active cluster species are in situ generated by apical ligand exchange reaction from aqueous media.
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Inorganic Chemistry issn: 0020-1669