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dc.contributor.author | Hevilla, Víctor | es_ES |
dc.contributor.author | Sonseca Olalla, Agueda | es_ES |
dc.contributor.author | Fernandez-Garcia, Marta | es_ES |
dc.date.accessioned | 2024-09-24T18:06:33Z | |
dc.date.available | 2024-09-24T18:06:33Z | |
dc.date.issued | 2023-07 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/208627 | |
dc.description.abstract | [EN] Enzymatic one-pot synthesis procedures in a one-step and two-step monomers addition were developed to obtain poly(glycerol adipate) macromers with methacrylate end-functional groups under the presence of 1 and 3 wt% of Candida antarctica lipase B (CALB). Glycerol, divinyl adipate, and vinyl methacrylate were enzymatically reacted (vinyl methacrylate was either present from the beginning in the monomers solution or slowly dropped after 6 h of reaction) in tetrahydrofuran (THF) at 40 °C over 48 h. Macromers with a methacrylate end groups fraction of ¿52% in a simple one-pot one-step procedure were obtained with molecular weights (Mn) of ¿7500-7900 g/mol. The obtained products under the one-pot one-step and two steps synthesis procedures carried out using 1 and 3 wt% of a CALB enzymatic catalyst were profusely characterized by NMR (1H and 13C), MALDI-TOF MS, and SEC. The methacrylate functional macromers obtained with the different procedures and 1 wt% of CALB were combined with an Irgacure® 369 initiator to undergo homopolymerization under UV irradiation for 10 and 30 min, in order to test their potential to obtain amorphous networks within minutes with similar properties to those typically obtained by complex acrylation/methacrylation procedures, which need multiple purification steps and harsh reagents such as acyl chlorides. To the best of our knowledge, this is the first time that it has been demonstrated that the obtention of methacrylate-functional predominantly linear macromers based on poly(glycerol adipate) is able to be UV crosslinked in a simple one-step procedure. | es_ES |
dc.description.sponsorship | This work was funded by the Ministerio de Ciencia e Innovacion (project PID2019-104600RB-I00), the Agencia Estatal de Investigacion (AEI, Spain), and Fondo Europeo de Desarrollo Regional (FEDER, EU) and by the Valencian Autonomous Government, Generalitat Valenciana, GVA (GV/2021/182). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | MDPI AG | es_ES |
dc.relation.ispartof | Polymers | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | UV-curing | es_ES |
dc.subject | Enzymatic synthesis | es_ES |
dc.subject | Functionalization | es_ES |
dc.subject | Poly(glycerol adipate) | es_ES |
dc.subject | Steps | es_ES |
dc.subject.classification | CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA | es_ES |
dc.title | Straightforward Enzymatic Methacrylation of Poly(Glycerol Adipate) for Potential Applications as UV Curing Systems | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/polym15143050 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104600RB-I00/ES/POLIMEROS SOSTENIBLES BIOBASADOS CON ACTIVIDAD ANTIMICROBIANA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//GV%2F2021%2F182/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Hevilla, V.; Sonseca Olalla, A.; Fernandez-Garcia, M. (2023). Straightforward Enzymatic Methacrylation of Poly(Glycerol Adipate) for Potential Applications as UV Curing Systems. Polymers. 15(14). https://doi.org/10.3390/polym15143050 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/polym15143050 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 15 | es_ES |
dc.description.issue | 14 | es_ES |
dc.identifier.eissn | 2073-4360 | es_ES |
dc.identifier.pmid | 37514438 | es_ES |
dc.identifier.pmcid | PMC10383392 | es_ES |
dc.relation.pasarela | S\524076 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |