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dc.contributor.author | Orellana-Silla, Alejandro | es_ES |
dc.contributor.author | Turo-Cortés, Rubén | es_ES |
dc.contributor.author | Meneses-Sánchez, Manuel | es_ES |
dc.contributor.author | Muñoz Roca, María Del Carmen | es_ES |
dc.contributor.author | Bartual-Murgui, Carlos | es_ES |
dc.contributor.author | Real, Jose Antonio | es_ES |
dc.date.accessioned | 2024-10-07T18:07:33Z | |
dc.date.available | 2024-10-07T18:07:33Z | |
dc.date.issued | 2024-09-05 | es_ES |
dc.identifier.issn | 0020-1669 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/209457 | |
dc.description.abstract | [EN] Integration of spin crossover (SCO) properties in 3D frameworks made up of cyano-bimetallic layers connected through pillaring organic ligands, the so-called Hofmann-type coordination polymers (HCPs)- represents an important source of multifunctional advanced materials. Typically, these 3D structures are constituted by 4-substituted pyridine-based linear pillars which afford HCPs with regular pcu topology. Here, we have investigated the suitability of the 3-substituted pyridine and pyrimidine bis-monodentate ligands 2,5-di(pyridin-3-yl)aniline (3-dpyan) and 2,5-di(pyrimidin-5-yl)aniline (bpmdan) as alternative building blocks to explore new structural topologies and functionalities. In this context, we have prepared the compounds Fe(3-dpyan)[Ag(CN)(2)](2)<middle dot>2MeOH (1(Ag)<middle dot>2MeOH), Fe(3-dpyan)[Ag(CN)(2)](2)<middle dot><middle dot><middle dot>0.35NO(2)Bz<middle dot>MeOH (1(Ag)<middle dot>0.35NO(2)Bz<middle dot>MeOH), Fe(3-dpyan)[Au(CN)(2)](2)<middle dot>NO(2)Bz (1(Au)<middle dot>NO(2)Bz), and Fe(bpmdan)[Ag(CN)(2)](2)<middle dot>CH(3)Bz (2(Ag)<middle dot>CH(3)Bz) (MeOH = methanol, NO(2)Bz = nitrobenzene, CH(3)Bz = toluene). Our structural studies have revealed that 1(Ag)<middle dot>2MeOH and 1(Ag)<middle dot>0.35NO(2)Bz<middle dot>MeOH exhibit isomorphous doubly interpenetrated 3D structures strongly differing from the unusual noninterpenetrated ones exhibited by 1(Au)<middle dot>NO(2)Bz and 2(Ag)<middle dot>CH(3)Bz. Temperature-dependent magnetic susceptibility measurements have shown that all the reported compounds exhibit thermal-induced SCO properties, and moreover, three of them display Light Induced Excited Spin State Trapping at low temperatures (LIESST effect). The studied compounds show a wide diversity of SCO behaviors, ranging from abrupt complete one-step SCO centered at 253 K (1(Au)<middle dot>NO(2)Bz) to gradual and incomplete multistepped SCO centered at 120 K (1(Ag)<middle dot>0.35NO(2)Bz<middle dot>MeOH). This assorted SCO properties are discussed and correlated to the acquired chemical and structural information. | es_ES |
dc.description.sponsorship | This work was supported by the Spanish Ministerio de Ciencia, Innovacion y Universidades (MICIU) through Grant PID2023-150732NB-I00 and Unidad de Excelencia Maria de Maeztu (CEX2019-000919-M). A.O.S. and R. T. C. thank MICIU for the predoctoral (FPI) grants PRE2020-092798 and PRE2018-084918, respectively. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Inorganic Chemistry | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Thermal and Light-Induced Spin Transitions in 3D Hofmann-type Frameworks Built on Nonlinear 3-Substituted Pyridine and Pyrimidine Pillaring Ligands | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/acs.inorgchem.4c03261 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MCIU//PID2023-150732NB-I00/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CEX2019-000919-M/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//PRE2020-092798/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//PRE2018-084918/ | es_ES |
dc.rights.accessRights | Embargado | es_ES |
dc.date.embargoEndDate | 2025-09-05 | es_ES |
dc.description.bibliographicCitation | Orellana-Silla, A.; Turo-Cortés, R.; Meneses-Sánchez, M.; Muñoz Roca, MDC.; Bartual-Murgui, C.; Real, JA. (2024). Thermal and Light-Induced Spin Transitions in 3D Hofmann-type Frameworks Built on Nonlinear 3-Substituted Pyridine and Pyrimidine Pillaring Ligands. Inorganic Chemistry. 63(37):17305-17315. https://doi.org/10.1021/acs.inorgchem.4c03261 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acs.inorgchem.4c03261 | es_ES |
dc.description.upvformatpinicio | 17305 | es_ES |
dc.description.upvformatpfin | 17315 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 63 | es_ES |
dc.description.issue | 37 | es_ES |
dc.identifier.pmid | 39235325 | es_ES |
dc.relation.pasarela | S\527109 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades | es_ES |