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dc.contributor.author | Bilanin-Artigado, Cristina | es_ES |
dc.contributor.author | Singh, Amravati Shivaji | es_ES |
dc.contributor.author | Martínez-Belenguer, Lluis | es_ES |
dc.contributor.author | Leyva Perez, Antonio | es_ES |
dc.date.accessioned | 2024-10-08T18:10:03Z | |
dc.date.available | 2024-10-08T18:10:03Z | |
dc.date.issued | 2024-08-05 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/209538 | |
dc.description.abstract | [EN] The direct synthesis of terminal alkynes from widely available terminal alkenes is an unmet challenge in organic synthesis. Here, we show that alkyl and aromatic terminal alkenes can be converted to the corresponding alkynes in a one-pot process consisting of a Ru-catalyzed dehydrogenative hydrosilylation, followed by an oxidative dehydrogenative reaction of the vinyl silane intermediate, enabled by the combination of PhIO with BF3. This formal alkene dehydrogenation reaction with commercially available reagents and under mild reaction conditions gives access to terminal alkynes in a simple manner, including acetylene. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Science and Innovation (CEX2021-001230-S grant funded by MCIN/AEI/10.13039/501100011033, and PID2020-115100GB-I00) is gratefully acknowledged. C.B. thanks ITQ/UPV-CSIC for a contract (PAID 01-20). A.S.S. also thanks ITQ for the concession of a contract. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | JACS Au | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Alkynes | es_ES |
dc.subject | Alkenes | es_ES |
dc.subject | One-pot reaction | es_ES |
dc.subject | Dehydrogenative hydrosilylation | es_ES |
dc.subject | Vinyl silane | es_ES |
dc.subject | Iodosobenzene | es_ES |
dc.subject | Ruthenium catalysis | es_ES |
dc.subject | Acetylene | es_ES |
dc.title | One-Pot Synthesis of Terminal Alkynes from Alkenes | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/jacsau.4c00599 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115100GB-I00/ES/CLUSTERES CATALITICOS MULTIMETALICOS Y DE ALTA ENTROPIA PARA SINTESIS ORGANICA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/ITQ//PAID 01-20/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//CEX2021-001230-S/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Bilanin-Artigado, C.; Singh, AS.; Martínez-Belenguer, L.; Leyva Perez, A. (2024). One-Pot Synthesis of Terminal Alkynes from Alkenes. JACS Au. 4(8):3284-3294. https://doi.org/10.1021/jacsau.4c00599 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/jacsau.4c00599 | es_ES |
dc.description.upvformatpinicio | 3284 | es_ES |
dc.description.upvformatpfin | 3294 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 4 | es_ES |
dc.description.issue | 8 | es_ES |
dc.identifier.eissn | 2691-3704 | es_ES |
dc.identifier.pmid | 39211598 | es_ES |
dc.identifier.pmcid | PMC11350724 | es_ES |
dc.relation.pasarela | S\526425 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Instituto de Tecnología Química UPV-CSIC | es_ES |