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Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon

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Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon

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dc.contributor.author Uscategui-Linares, Andrés Felipe es_ES
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author Parvulescu, Vasile es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2025-02-27T19:03:01Z
dc.date.available 2025-02-27T19:03:01Z
dc.date.issued 2024-07-15 es_ES
dc.identifier.issn 2468-8231 es_ES
dc.identifier.uri http://hdl.handle.net/10251/214921
dc.description.abstract [EN] The development of heterogeneous catalysts for hydrocarbon oxidation by molecular oxygen as oxidant is an area of increasing interest from academia and chemical industry points of views. Herein, the catalytic activity of two-dimensional (2D) porphyrin metal -organic frameworks (MOFs) constituted by Co 2 + , Cu 2 + or Mn 3 + as transition metal ions coordinated to tetra(4-carboxyphenyl)porphyrin (TCPP) organic ligand as heterogeneous catalysts for the aerobic oxidation of benzylic hydrocarbon oxidation is reported. Selective radical quenching experiments and in -situ Raman measurements reveal the formation of superoxide/hydroperoxide and hydroxyl radicals during the catalytic reaction using Co-CoTCPP. es_ES
dc.description.sponsorship Financial support the Spanish Ministry of Science and Innovation (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Generation EU, through the Conselleria de Innovacion, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU) .r (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Gen-eration EU, through the Conselleria de Innovaci on, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Uni-versities, financed by the European Union, NextGeneration EU) . es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Molecular Catalysis es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Aerobic oxidation es_ES
dc.subject Indane es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal organic frameworks es_ES
dc.subject Two-dimensional es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.mcat.2024.114288 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123856OB-I00/ES/FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AGENCIA ESTATAL DE INVESTIGACION//CEX2021-001230-S//CENTRO DE EXCELENCIA SEVERO OCHO INSTITUTO DE TECNOLOGIA QUIMICA (ITQ)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2021%2F038/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//MFA%2F2022%2F023/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//RYC2021-031006-I/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Uscategui-Linares, AF.; Santiago-Portillo, A.; Navalón Oltra, S.; Dhakshinamoorthy, A.; Albero-Sancho, J.; Parvulescu, V.; García Gómez, H. (2024). Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon. Molecular Catalysis. 564. https://doi.org/10.1016/j.mcat.2024.114288 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.mcat.2024.114288 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 564 es_ES
dc.relation.pasarela S\523048 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
upv.costeAPC 2840 es_ES


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