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Intermolecular [2 + 2] cycloaddition of alkene catalyzed by Au(I) complexes. What are the catalytic sites involved?

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Intermolecular [2 + 2] cycloaddition of alkene catalyzed by Au(I) complexes. What are the catalytic sites involved?

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Grirrane ., A.; García Gómez, H.; Corma Canós, A.; Alvarez, E. (2011). Intermolecular [2 + 2] cycloaddition of alkene catalyzed by Au(I) complexes. What are the catalytic sites involved?. ACS CATALYSIS. 1(12):1647-1653. doi:10.1021/cs2004278

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Título: Intermolecular [2 + 2] cycloaddition of alkene catalyzed by Au(I) complexes. What are the catalytic sites involved?
Autor:
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
: Bulky Au(I) biphenylphosphine complexes form with phenylacetylene isolable digold complexes under conditions of the room-temperature intermolecular [2 + 2] cycloaddition of phenylacetylene and ¿-methylstyrene. Singlecrystal ...[+]
Palabras clave: Homogeneous gold catalysis , Cycloaddition reaction , Diaurate complex as catalyst , Au(I) complex as precatalyst
Derechos de uso: Cerrado
Fuente:
ACS CATALYSIS. (issn: 2155-5435 )
DOI: 10.1021/cs2004278
Editorial:
American Chemical Society
Versión del editor: http://dx.doi.org/10.1021/cs2004278
Agradecimientos:
Financial support by Spanish Ministry of Science and Innovation (Consolider MULTICAT and CTQ 2009-11586) is gratefully acknowledged. The Generalidad Valenciana is also thanked for partial financial support (Prometeo Grant).[+]
Tipo: Artículo

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