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Synthesis of Organic-Inorganic Hybrid Solids with Copper Complex Framework and Their Catalytic Activity for the S-Arylation and the Azide-Alkyne Cycloaddition Reactions

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Synthesis of Organic-Inorganic Hybrid Solids with Copper Complex Framework and Their Catalytic Activity for the S-Arylation and the Azide-Alkyne Cycloaddition Reactions

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dc.contributor.author Cabrero Antonino, Jose Ramón es_ES
dc.contributor.author García Fernández, María Teresa es_ES
dc.contributor.author Rubio Marqués, Paula es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Al-Deyab, Salem S. es_ES
dc.contributor.author Al-Resayes, Saud I. es_ES
dc.contributor.author Díaz Morales, Urbano Manuel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-04-17T07:11:05Z
dc.date.issued 2011
dc.identifier.issn 2155-5435
dc.identifier.uri http://hdl.handle.net/10251/27944
dc.description.abstract [EN] Two di¿erent diamines, namely, Tr¿oger base and dimethylethylene diamine (DMEDA) functionalized with disilane groups, have been condensed with silica precursors to form mesoporous hybrid organic-inorganic materials. After introduction of copper, the Cu-diamine complexes are produced. These hybrid solids have been fully characterized and are active catalysts for the S-arylation of aryl iodides and bromides with thiophenols and disul¿des. Additionally, the hybrids show catalytic activity for the cycloaddition reaction between azides and phenylacetylenes. The reaction conditions determine the recovery and reuse of the solid. es_ES
dc.description.sponsorship Financial support by Consolider-Ingenio 2010 (proyecto MUL-TICAT) and PLE2009 project from MCIINN and King Saud University are acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS CATALYSIS es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Hybrid solid es_ES
dc.subject Copper es_ES
dc.subject Catalysis es_ES
dc.subject S-arylation es_ES
dc.subject Troger Base es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of Organic-Inorganic Hybrid Solids with Copper Complex Framework and Their Catalytic Activity for the S-Arylation and the Azide-Alkyne Cycloaddition Reactions es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/cs100086y
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Cabrero Antonino, JR.; García Fernández, MT.; Rubio Marqués, P.; Vidal Moya, JA.; Leyva Perez, A.; Al-Deyab, SS.; Al-Resayes, SI.... (2011). Synthesis of Organic-Inorganic Hybrid Solids with Copper Complex Framework and Their Catalytic Activity for the S-Arylation and the Azide-Alkyne Cycloaddition Reactions. ACS CATALYSIS. 1(2):147-158. https://doi.org/10.1021/cs100086y es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/ipdf/10.1021/cs100086y es_ES
dc.description.upvformatpinicio 147 es_ES
dc.description.upvformatpfin 158 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 1 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 39849
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder King Saud University, Arabia Saudí


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