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dc.contributor.author | Nikolla, Eranda | es_ES |
dc.contributor.author | Román-Leshkov, Yuriy | es_ES |
dc.contributor.author | Moliner Marin, Manuel | es_ES |
dc.contributor.author | Davis, Mark E. | es_ES |
dc.date.accessioned | 2013-04-17T07:18:42Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | http://hdl.handle.net/10251/27945 | |
dc.description.abstract | [EN] Conversion of carbohydrates to 5-(hydroxymethyl)furfural (HMF) may provide a step forward toward achieving a renewable biomass-based chemicals and fuels platform. Recently, we reported that a tin-containing, high-silica molecular sieve with the zeolite beta topology (Sn-Beta) can efficiently catalyze the isomerization of glucose to fructose in aqueous media at low pH. Herein, we describe the combination of Sn-Beta with acid catalysts in a one vessel, biphasic reactor system to synthesize HMF from carbohydrates such as glucose, cellobiose, and starch with high efficiency. HMF selectivities over 70% were obtained using this ¿one-pot¿ biphasic water/tetrahydrofuran (THF) reactor system. The key to successfully achieving the conversions/selectivities reported is that Sn-Beta is able to convert glucose to fructose at pH near 1 and in saturated aqueous salt solutions. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS CATALYSIS | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Zeolite | es_ES |
dc.subject | HMF | es_ES |
dc.subject | Carbohydrate conversion | es_ES |
dc.subject | Glucose isomerization | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.title | "One-pot" synthesis of 5-(Hydroxymethyl)furfural from carbohydrates using tin-Beta zeolite | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/cs2000544 | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Nikolla, E.; Román-Leshkov, Y.; Moliner Marin, M.; Davis, ME. (2011). "One-pot" synthesis of 5-(Hydroxymethyl)furfural from carbohydrates using tin-Beta zeolite. ACS CATALYSIS. 1:408-410. doi:10.1021/cs2000544 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://pubs.acs.org/doi/ipdf/10.1021/cs2000544 | es_ES |
dc.description.upvformatpinicio | 408 | es_ES |
dc.description.upvformatpfin | 410 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 1 | es_ES |
dc.relation.senia | 193867 |