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Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO

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Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO

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dc.contributor.author Amarajothi, Dhakshina Moorthy es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2013-04-17T07:24:10Z
dc.date.issued 2011
dc.identifier.issn 2155-5435
dc.identifier.uri http://hdl.handle.net/10251/27947
dc.description.abstract [EN] Cu3 (BTC)2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an e¿ective and reusable heterogeneous catalyst to e¿ect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding benzaldehydes under mild temperature at atmospheric pressure. The main deactivation process was attributed to the formation of carboxylic acids arising from the overoxidation of the aromatic aldehyde acting as poisons, coordinating to the free Cu(II) sites and blocking the pores. Comparison with copper acetate as a soluble, homogeneous system established that immobilization of the Cu(II) in the rigid crystal structure of Cu3 (BTC)2 does not diminish the intrinsic catalytic activity of this transition metal ion. es_ES
dc.description.sponsorship Financial support by the Spanish DGI (CTQ06-6857 and CTQ2007-67805) is gratefully acknowledged. The European Commission Integrated Project (MACADEMIA, FP7 no 228862) is also acknowledged for partial financial assistance. en_EN
dc.language Español es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS CATALYSIS es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cu3 (BTC)2 es_ES
dc.subject Alcohol oxidation es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject TEMPO es_ES
dc.subject Copper es_ES
dc.subject Aerobic oxidation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/cs1000703
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CTQ06-6857/ en_EN
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CTQ2007-67805/ES/APLICACION DE NUEVOS DERIVADOS DEL PPV ENCAPSULADOS EN MATRICES DE SILICE EN LA PREPARACION DE TRANSISTORES DE CAMPO ELECTRICO Y RECTIFICADORES A ESCALA MICROMETRICA/ en_EN
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Amarajothi, DM.; Alvaro Rodríguez, MM.; García Gómez, H. (2011). Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO. ACS CATALYSIS. 1(1):48-53. https://doi.org/10.1021/cs1000703 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/ipdf/10.1021/cs1000703 es_ES
dc.description.upvformatpinicio 48 es_ES
dc.description.upvformatpfin 53 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 1 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 215901
dc.contributor.funder European Commission
dc.contributor.funder Ministerio de Educación y Ciencia es_ES


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