Pérez Ruiz, R.; Domingo, LR.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction. Organic Letters. 13(19):5116-5119. doi:10.1021/ol201984s
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/28114
Title:
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Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction
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Author:
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Pérez Ruiz, Raul
Domingo, Luis R
Jiménez Molero, María Consuelo
Miranda Alonso, Miguel Ángel
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UPV Unit:
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Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
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Issued date:
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Abstract:
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[EN] The feasibility of an electron transfer imino-Diels Alder reaction betweenN-benzylideneaniline and arylalkenes in the presence of a pyrylium salt
as a photosensitizer has been demonstrated by a combination of product ...[+]
[EN] The feasibility of an electron transfer imino-Diels Alder reaction betweenN-benzylideneaniline and arylalkenes in the presence of a pyrylium salt
as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations.
A stepwise mechanism involving two intermediates and two transition states is proposed.
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Subjects:
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Photoinduced electron-transfer
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Tetrahydroquinoline derivatives
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2,4,6-triphenylpyrylium salt
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4+2 cycloaddition; martinellic acid
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Facile synthesis
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N-Arylimines
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Thiobenzophenone
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Mechanisms
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Catalysis
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Copyrigths:
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Cerrado |
Source:
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Organic Letters. (issn:
1523-7060
)
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DOI:
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10.1021/ol201984s
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Publisher:
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American Chemical Society
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Publisher version:
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http://pubs.acs.org/doi/ipdf/10.1021/ol201984s
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Project ID:
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MICINN/CTQ2010-14882
MICINN/CTQ2009-11027
MICINN/JCI-2010-06204
UPV/20100994
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Thanks:
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Financial support from the MICINN (Grants CTQ2010-14882, CTQ2009-13699, CTQ2009-11027, and JCI-2010-06204) and from the UPV (Grant No. 20100994 and MCI Program) is gratefully acknowledged. Dedicated to Prof. Dr. Jaime Primo ...[+]
Financial support from the MICINN (Grants CTQ2010-14882, CTQ2009-13699, CTQ2009-11027, and JCI-2010-06204) and from the UPV (Grant No. 20100994 and MCI Program) is gratefully acknowledged. Dedicated to Prof. Dr. Jaime Primo (Universidad Politecnica de Valencia) on the occasion of his 60th birthday.
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Type:
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Artículo
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