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Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene

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Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene

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Alonso Ruiz, R.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene. Organic Letters. 13(15):3860-3863. https://doi.org/10.1021/ol201209h

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/28116

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Title: Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene
Author: Alonso Ruiz, Rafael Jiménez Molero, María Consuelo Miranda Alonso, Miguel Ángel
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are ...[+]
Subjects: Human-serum-albumin , Transient absorption-spectroscopy , Human alpha(1)-acid glycoprotein , Anti-markovnikov photoaddition , Triplet excited-state , Enantiodifferentiating photocyclodimerization , Supramolecular photochirogenesis , 9-substituted anthracenes , Asymmetric photochemistry , Gamma-cyclodextrins
Copyrigths: Cerrado
Source:
Organic Letters. (issn: 1523-7060 )
DOI: 10.1021/ol201209h
Publisher:
American Chemical Society
Publisher version: http://pubs.acs.org/doi/ipdf/10.1021/ol201209h
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2010-14882/ES/DIADAS FOTOACTIVAS COMO SONDAS PARA LA GENERACION DE ESPECIES TRANSITORIAS EN SISTEMAS MICROHETEROGENEOS DE TIPO BIOMIMETICO/
info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/
Thanks:
Financial support from the MICINN (Grant CTQ2010-14882), the Generalitat Valenciana (Prometeo Program, ref 2008/090), and the Carlos III Institute of Health (Red RETICS) is gratefully acknowledged. We also thank Dr. A. ...[+]
Type: Artículo

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