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Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study

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Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study

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Beltran, TF.; Feliz Rodriguez, M.; Llusar, R.; Mata, JA.; Safont, VS. (2011). Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study. Organometallics. 30(2):290-297. https://doi.org/10.1021/om1009878

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/28122

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Title: Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study
Author: Beltran, Tomas F. Feliz Rodriguez, Marta Llusar, Rosa Mata, Jose A. Safont, Vicent S.
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] The catalytic hydrodefluorination (HDF) of pentafluoropyridine in the presence of arylsilanes is catalyzed by the tungsten and molybdenum(IV) cluster hydrides of formula [M3 S4 H3(dmpe)3] ¿, W-1¿for M = W and Mo-1¿for ...[+]
Subjects: Carbon-fluorine bonds , C-F bond , Acid-assisted substitution , Potential basis-sets , Polarization functions , Coordinated hydrides , Proton-transfer , Oxidative addition , Metal-complexes , Cubane cluster
Copyrigths: Cerrado
Source:
Organometallics. (issn: 0276-7333 )
DOI: 10.1021/om1009878
Publisher:
American Chemical Society
Publisher version: http://pubs.acs.org/doi/ipdf/10.1021/om1009878
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2008-02670/ES/NUEVOS ASPECTOS SOBRE LA QUIMICA DE LOS CALCOGENUROS CLUSTER DE METALES DE TRANSICION DIRIGIDOS A SUS APLICACIONES EN CATALISIS Y ELECTRONICA MOLECULAR/
Fundacio Bancaixa-UJI/P1.1B2007-12
GV/ACOMP/2010/276
GV/PROMETEO/2009/053
Thanks:
The financial support of the Spanish Ministerio de Ciencia e Innovacion (Grants CTQ2008-02670), Fundacio Bancaixa-UJI (research project P1.1B2007-12), and Generalitat Valenciana (ACOMP/2010/276 and Prometeo/2009/053) is ...[+]
Type: Artículo

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