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Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study

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Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study

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Beltran, TF.; Feliz Rodriguez, M.; Llusar, R.; Mata, JA.; Safont, VS. (2011). Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study. Organometallics. 30(2):290-297. doi:10.1021/om1009878

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/28122

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Título: Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
[EN] The catalytic hydrodefluorination (HDF) of pentafluoropyridine in the presence of arylsilanes is catalyzed by the tungsten and molybdenum(IV) cluster hydrides of formula [M3 S4 H3(dmpe)3] ¿ , W-1¿ for M = W and ...[+]
Palabras clave: Carbon-fluorine bonds , C-F bond , Acid-assisted substitution , Potential basis-sets , Polarization functions , Coordinated hydrides , Proton-transfer , Oxidative addition , Metal-complexes , Cubane cluster
Derechos de uso: Cerrado
Fuente:
Organometallics. (issn: 0276-7333 )
DOI: 10.1021/om1009878
Editorial:
American Chemical Society
Versión del editor: http://pubs.acs.org/doi/ipdf/10.1021/om1009878
Tipo: Artículo

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