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New sandwich and half-sandwich titanium hydrazido compounds

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New sandwich and half-sandwich titanium hydrazido compounds

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Selby, JD.; Feliz Rodriguez, M.; Schwarz, AD.; Clot, E.; Mountford, P. (2011). New sandwich and half-sandwich titanium hydrazido compounds. Organometallics. 30:2295-2307. doi:10.1021/om200068k

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Title: New sandwich and half-sandwich titanium hydrazido compounds
Author: Selby, Jonathan D. Feliz Rodriguez, Marta Schwarz, Andrew D. Clot, Eric Mountford, Philip
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
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[EN] New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N'-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(N(t)Bu)Cl(PY) (1) with Ph(2)NNH(2) ...[+]
Subjects: N-N bond , Ray crystal-structures , Potential basis-sets , Transition-metal , Imido compounds , Cycloaddition reactions , Polarization functions , Electronic-structure , Trapping reactions , Functional-group
Copyrigths: Cerrado
Organometallics. (issn: 0276-7333 )
DOI: 10.1021/om200068k
American Chemical Society
Publisher version: http://pubs.acs.org/doi/ipdf/10.1021/om200068k
We thank the EPSRC, British Council, MESR, and the Spanish Ministerio de Educacion y Ciencia for support. We thank Andrew Cowley for help with some of the X-ray structures.
Type: Artículo

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