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Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies

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Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies

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Bruijnincx Pieter C. A; Buurmans, ILC.; Huang, Y.; Juhász, G.; Viciano-Chumillas, M.; Quesada Vilar, M.; Reedijk, J.... (2011). Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies. Inorganic Chemistry. 9243-9255. doi:10.1021/ic200332y

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/28137

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Title: Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies
Author: Bruijnincx Pieter C. A Buurmans, Inge L. C Huang, Yuxing Juhász, Gergely Viciano-Chumillas, Marta Quesada Vilar, Manuel Reedijk, Jan Lutz, Martin Spek, Anthony L. Munck, Eckard Bominaar, Emile L. Klein Gebbink, Robertus J. M.
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] The newly synthesized dinuclear complex [Fe-2(III)(mu-OH)(2)(bik)(4)](NO3)(4) (1) (bik, bis(1-methylimidazol-2-yl)ketone) shows rather short Fe center dot center dot center dot Fe (3.0723(6) angstrom) and Fe-O distances ...[+]
Subjects: 2-HIS-1-carboxylate facial , Bridged diiron(III) complexes , Alkane oxidation , Biomimetic nonheme iron , Crystal-structures , Ribonucleotide reductase
Copyrigths: Reserva de todos los derechos
Source:
Inorganic Chemistry. (issn: 0020-1669 )
DOI: 10.1021/ic200332y
Publisher:
American Chemical Society
Publisher version: http://doi.org/10.1021/ic200332y
Thanks:
This work was financially supported by the National Research School Combination-Catalysis (P.C.A.B.), the Council for Chemical Sciences of The Netherlands Organization for Scientific Research (CW-NWO) (M.L. and A.L.S.), ...[+]
Type: Artículo

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