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A New Aluminosilicate Molecular Sieve with a System of Pores between Those of ZSM-5 and Beta Zeolite

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A New Aluminosilicate Molecular Sieve with a System of Pores between Those of ZSM-5 and Beta Zeolite

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dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Gonzalez, Jorge es_ES
dc.contributor.author Portilla Ovejero, Mª Teresa es_ES
dc.contributor.author Willhammar, Tom es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Llopis Alonso, Francisco Javier es_ES
dc.contributor.author Zou, Xiaodong es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-05-08T11:07:01Z
dc.date.issued 2011-06
dc.identifier.issn 0002-7863
dc.identifier.uri http://hdl.handle.net/10251/28679
dc.description.abstract [EN] A new aluminosilicate zeolite (ITQ-39) has been synthesized. This is an extensively faulted structure with very small domains that makes the structure elucidation very difficult. However, a combination of adsorption spectroscopy and reactivity studies with selected probe molecules suggests that the pore structure of ITQ-39 is related to that of Beta zeolite, with a three-directional channel system with large pores (12-MR), but with an effective pore diameter between those of Beta and ZSM-5, or a three-directional channel system with interconnected large (12-MR) and medium pores (10-MR). The pore topology of ITQ-39 is very attractive for catalysis and shows excellent results for the preparation of cumene by alkylation of benzene, while it can be a promising additive for FCC. es_ES
dc.description.sponsorship Financial support by the Spanish MICINN (MAT2009-14528-C02-01), Consolider Ingenio 2010-MULTICAT, Swedish Research Council (VR), the Swedish Governmental Agency for Innovation Systems (VINNOVA), and the Goran Gustafsson Foundation is gratefully acknowledged. Generalitat Valenciana is also thanked for funding through the Prometeo program. M.T.P. gratefully acknowledges CSIC for a JAE fellowship. The Knut and Alice Wallenberg Foundation for a grant for purchasing the TEMs used in this work is also thanked. en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Journal of the American Chemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A New Aluminosilicate Molecular Sieve with a System of Pores between Those of ZSM-5 and Beta Zeolite es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ja2015394
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14528-C02-01/ES/Sintesis, Caracterizacion Avanzada Y Empleo En Procesos Industriales De Nuevas Zeolitas Obtenidos Con Cationes Organicos No Convencionales Como Agentes Directores De Estructura/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Moliner Marin, M.; Gonzalez, J.; Portilla Ovejero, MT.; Willhammar, T.; Rey Garcia, F.; Llopis Alonso, FJ.; Zou, X.... (2011). A New Aluminosilicate Molecular Sieve with a System of Pores between Those of ZSM-5 and Beta Zeolite. Journal of the American Chemical Society. 133(24):9497-9505. https://doi.org/10.1021/ja2015394 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1021/ja2015394 es_ES
dc.description.upvformatpinicio 9497 es_ES
dc.description.upvformatpfin 9505 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 133 es_ES
dc.description.issue 24 es_ES
dc.relation.senia 41517
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Generalitat Valenciana


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