- -

Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

  • Estadisticas de Uso

Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes

Show simple item record

Files in this item

[Cerrado]
Name: ACS_Catal_2(1)_12 ...
Size: 323.0Kb
Format: PDF
Request a copy of the document
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Doménech, Antonio es_ES
dc.contributor.author Al-Resayes, Saud I. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-06-10T09:42:20Z
dc.date.issued 2011-12
dc.identifier.issn 2155-5435
dc.identifier.uri http://hdl.handle.net/10251/29552
dc.description.abstract [EN] Au(I)/Au(III) catalytic cycles are catalytically competent to perform the oxidative coupling of alkynes in the homogeneous phase at room temperature and without any protecting atmosphere. Selectfluor as oxidant, wet acetonitrile as solvent, and sodium carbonate as base are the reagents of choice. Both aromatic and alkyl alkynes can be coupled, and mechanistic studies reveal that at least two gold species having different oxidation states are implicated in the key step of the coupling. es_ES
dc.description.sponsorship A.L.-P. thanks CSIC for a contract. Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT), PLE2009 project from MCIINN, and King Saud University is also acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Gold catalysis es_ES
dc.subject Oxidative coupling of alkynes es_ES
dc.subject Redox chemistry es_ES
dc.subject Diynes es_ES
dc.subject Voltammetry es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/cs200532c
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Leyva Perez, A.; Doménech, A.; Al-Resayes, SI.; Corma Canós, A. (2011). Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes. ACS Catalysis. 2(1):121-126. https://doi.org/10.1021/cs200532c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1021/cs200532c
dc.description.upvformatpinicio 121 es_ES
dc.description.upvformatpfin 126 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 234689
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Consejo Superior de Investigaciones Científicas


This item appears in the following Collection(s)

Show simple item record