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dc.contributor.author | Corma Canós, Avelino![]() |
es_ES |
dc.contributor.author | Navas Escrig, Javier![]() |
es_ES |
dc.contributor.author | Sabater Picot, Mª José![]() |
es_ES |
dc.date.accessioned | 2013-06-10T12:27:36Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10251/29577 | |
dc.description.abstract | [EN] A one-pot reaction was performed with a nanoparticulated gold catalyst. A secondary amine is formed through N-monoalkylation of a primary amine with an alcohol by a borrowing hydrogen methodology in a three-step reaction. The secondary amine formed enters into a second A3-coupling cycle to give propargylamines. The multistep reaction requires a gold species formed and stabilized on a ceria surface. | es_ES |
dc.description.sponsorship | Financial support by the Direccion General de Investigacion Cientifica y Tecnica of Spain (Projects Consolider-Ingenio 2009 MIYCIN (CSD2009-00050) and MAT2011-28009). | |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | Chemistry - A European Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Alkylation | es_ES |
dc.subject | Domino reactions | es_ES |
dc.subject | Gold | es_ES |
dc.subject | Hydrogen transfer | es_ES |
dc.subject | Propargylamine | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Coupling two multistep catalytic cycles for the one-pot synthesis of propargylamines from alcohols and primary amines on nanoparticulated gold catalyst | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/chem.201201837 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2011-28009/ES/CATALIZADORES MONO- Y MULTIFUNCIONALES BASADOS EN NANOPARTICULAS METALICAS DIRIGIDOS A TRANSFORMACIONES SECUENCIALES O REACCIONES EN CASCADA/ | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Corma Canós, A.; Navas Escrig, J.; Sabater Picot, MJ. (2012). Coupling two multistep catalytic cycles for the one-pot synthesis of propargylamines from alcohols and primary amines on nanoparticulated gold catalyst. Chemistry - A European Journal. 18(44):14150-14156. https://doi.org/10.1002/chem.201201837 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/chem.201201837 | es_ES |
dc.description.upvformatpinicio | 14150 | es_ES |
dc.description.upvformatpfin | 14156 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 18 | es_ES |
dc.description.issue | 44 | es_ES |
dc.relation.senia | 234801 | |
dc.identifier.pmid | 22996294 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación |