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Asymmetric counteranion-directed catalytic hosomi-sakurai reaction

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Asymmetric counteranion-directed catalytic hosomi-sakurai reaction

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Mahlau, M.; García García, P.; List, B. (2012). Asymmetric counteranion-directed catalytic hosomi-sakurai reaction. Chemistry - A European Journal. 18(51):16283-16287. doi:10.1002/chem.201203623

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Title: Asymmetric counteranion-directed catalytic hosomi-sakurai reaction
Author: Mahlau, Manuel García García, Pilar List, Benjamin
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Counteranion control enables the enantioselective, organo Lewis acid catalyzed Hosomi¿Sakurai reaction of (hetero)aromatic aldehydes and allylsilanes using an easily handled disulfonimide precatalyst (see scheme). The ...[+]
Subjects: Allylation , Asymmetric catalysis , Disulfonimide catalysis , Hosomi-Sakurai reaction , Organocatalysis , Organo Lewis acid catalysis
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201203623
Publisher:
Wiley-VCH Verlag
Publisher version: http://dx.doi.org/10.1002/chem.201203623
Thanks:
We thank Melanie Gossens for technical support. Furthermore, help from our analytical departments, especially our GC and MS facilities is gratefully acknowledged. We thank the Max Planck Society, the European Research ...[+]
Type: Artículo

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