Rajabi, F.; Naserian, S.; Primo Arnau, AM.; Luque, R. (2011). Efficient and Highly Selective Aqueous oxidation of sulfides to sulfoxides at room temperature catalysed by supported iron oxide nanoparticles on SBA-15. Advanced Synthesis and Catalysis. 353:2060-2066. https://doi.org/10.1002/adsc.201100149
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/30018
Title:
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Efficient and Highly Selective Aqueous oxidation of sulfides to sulfoxides at room temperature catalysed by supported iron oxide nanoparticles on SBA-15
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Author:
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Rajabi, Fatemeh
Naserian, Sareh
Primo Arnau, Ana María
Luque, Rafael
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UPV Unit:
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Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
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Issued date:
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Abstract:
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The present manuscript describes a simple,
efficient and environmentally friendly room temperature aqueous catalytic approach to the selective
preparation of sulfoxides from sulfides utilising lowloaded supported iron ...[+]
The present manuscript describes a simple,
efficient and environmentally friendly room temperature aqueous catalytic approach to the selective
preparation of sulfoxides from sulfides utilising lowloaded supported iron oxide nanoparticles and aqueous hydrogen peroxide as oxidant. Materials could
be easily recovered from the reaction mixture and
reused ten times without any loss in activity and no
metal leaching was observed during the reaction.
This is thus the first selective aqueous oxidation of
sulfides using an iron-based heterogeneous system.
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Subjects:
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Aqueous chemistry
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Heterogeneous catalysis
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Room temperature reactions
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SBA-15
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Sulfide oxidation
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Supported iron oxide nanoparticles
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Copyrigths:
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Cerrado |
Source:
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Advanced Synthesis and Catalysis. (issn:
1615-4150
)
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DOI:
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10.1002/adsc.201100149
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Publisher:
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Wiley-VCH Verlag
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Publisher version:
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http://onlinelibrary.wiley.com/doi/10.1002/adsc.201100149/pdf
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Project ID:
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info:eu-repo/grantAgreement/MICINN//RYC-2009-04199/ES/RYC-2009-04199/
info:eu-repo/grantAgreement/Junta de Andalucía//P10-FQM-6711/
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Thanks:
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FR is grateful to Payame Noor University and Iran National Science Foundation (INSF) for support of this work. RL gratefully acknowledges support from Ministerio de Ciencia e Innovacion, Gobierno de Espana through a Ramon ...[+]
FR is grateful to Payame Noor University and Iran National Science Foundation (INSF) for support of this work. RL gratefully acknowledges support from Ministerio de Ciencia e Innovacion, Gobierno de Espana through a Ramon y Cajal contract (ref. RYC-2009-04199) and funding from Consejeria de Ciencia e Innovacion, Junta de Andalucia (project P10-FQM-6711).
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Type:
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Artículo
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