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dc.contributor.author | Leyva Perez, Antonio | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2013-06-27T08:17:13Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | http://hdl.handle.net/10251/30228 | |
dc.description.abstract | [EN] Relativistic effects in the valence shell of the elements reach a maximum in the triad Pt¿Au¿Hg and determine their catalytic activity in organic reactions. In this Review we examine the catalytic activity of Pt, Au, and Hg compounds for some representative reactions, and discuss the respective benefits and disadvantages along with other relevant properties, such as toxicity, price, and availability. For the reactions considered, gold catalysts are generally more active than mercury or platinum catalysts. | es_ES |
dc.description.sponsorship | A.L.-P. thanks CSIC for a contract under JAE-doctors program. Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT) and PLE2009 project from MCIINN is also acknowledged. | |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Catalysis | es_ES |
dc.subject | Gold | es_ES |
dc.subject | Mercury | es_ES |
dc.subject | Platinum | es_ES |
dc.subject | Highly efficient catalysts | es_ES |
dc.subject | Transition-metal catalysts | es_ES |
dc.subject | Low-temperature oxidation | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/anie.201101726 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Leyva Perez, A.; Corma Canós, A. (2012). Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis. Angewandte Chemie International Edition. 51(3):614-635. doi:10.1002/anie.201101726 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/anie.201101726 | es_ES |
dc.description.upvformatpinicio | 614 | es_ES |
dc.description.upvformatpfin | 635 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 51 | es_ES |
dc.description.issue | 3 | es_ES |
dc.relation.senia | 209232 | |
dc.identifier.pmid | 22086868 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación |