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Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis

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Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis

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dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-06-27T08:17:13Z
dc.date.issued 2012
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/30228
dc.description.abstract [EN] Relativistic effects in the valence shell of the elements reach a maximum in the triad Pt¿Au¿Hg and determine their catalytic activity in organic reactions. In this Review we examine the catalytic activity of Pt, Au, and Hg compounds for some representative reactions, and discuss the respective benefits and disadvantages along with other relevant properties, such as toxicity, price, and availability. For the reactions considered, gold catalysts are generally more active than mercury or platinum catalysts. es_ES
dc.description.sponsorship A.L.-P. thanks CSIC for a contract under JAE-doctors program. Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT) and PLE2009 project from MCIINN is also acknowledged.
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Catalysis es_ES
dc.subject Gold es_ES
dc.subject Mercury es_ES
dc.subject Platinum es_ES
dc.subject Highly efficient catalysts es_ES
dc.subject Transition-metal catalysts es_ES
dc.subject Low-temperature oxidation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201101726
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Leyva Perez, A.; Corma Canós, A. (2012). Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis. Angewandte Chemie International Edition. 51(3):614-635. doi:10.1002/anie.201101726 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201101726 es_ES
dc.description.upvformatpinicio 614 es_ES
dc.description.upvformatpfin 635 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 51 es_ES
dc.description.issue 3 es_ES
dc.relation.senia 209232
dc.identifier.pmid 22086868
dc.contributor.funder Ministerio de Ciencia e Innovación


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