- -

(3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3, 4-dihydro-2Hpyrrole 1-oxide

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

(3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3, 4-dihydro-2Hpyrrole 1-oxide

Show full item record

Flores, M.; García García, P.; Garrido, N.; Sanz, F.; Diez, D. (2011). (3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3, 4-dihydro-2Hpyrrole 1-oxide. Acta Crystallographica Section E. 67:1115-1115. doi:10.1107/S1600536811010737

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/30411

Files in this item

Item Metadata

Title: (3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3, 4-dihydro-2Hpyrrole 1-oxide
Author:
Issued date:
Abstract:
[EN] The title compound, C14H17NO5S, was prepared by oxidation of (2R,3S,4R)-2-phenylsulfonylmethyl-1-hydroxy-3,4-isopropylidenedioxypyrrolidine. Its crystal structure confirms unequivocally its configuration. Two ...[+]
Subjects: Michael Addition , Aldehydes
Copyrigths: Reconocimiento (by)
Source:
Acta Crystallographica Section E. (issn: 1600-5368 )
DOI: 10.1107/S1600536811010737
Publisher:
International Union of Crystallography
Publisher version: http://scripts.iucr.org/cgi-bin/paper?S1600536811010737
Thanks:
The authors are grateful to the MICINN (CTQ2009-1172), Junta de Castilla y Leon for financial support (GR178 and SA001A09) and for the doctoral fellowships awarded to MFF.
Type: Artículo

References

Andrey, O., Alexakis, A., Tomassini, A., & Bernardinelli, G. (2004). The Use ofN-Alkyl-2,2′-bipyrrolidine Derivatives as Organocatalysts for the Asymmetric Michael Addition of Ketones and Aldehydes to Nitroolefins. Advanced Synthesis & Catalysis, 346(910), 1147-1168. doi:10.1002/adsc.200404037

Berkessel, A. & Groger, H. (2005). Asymmetric Organocatalysis. From Biomimetic Concepts to Applications in Asymmetric Synthesis. Weinheim: Wiley-VCH.

Bruker (2006). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA. [+]
Andrey, O., Alexakis, A., Tomassini, A., & Bernardinelli, G. (2004). The Use ofN-Alkyl-2,2′-bipyrrolidine Derivatives as Organocatalysts for the Asymmetric Michael Addition of Ketones and Aldehydes to Nitroolefins. Advanced Synthesis & Catalysis, 346(910), 1147-1168. doi:10.1002/adsc.200404037

Berkessel, A. & Groger, H. (2005). Asymmetric Organocatalysis. From Biomimetic Concepts to Applications in Asymmetric Synthesis. Weinheim: Wiley-VCH.

Bruker (2006). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

Cicchi, S., Marradi, M., Goti, A., & Brandi, A. (2001). Manganese dioxide oxidation of hydroxylamines to nitrones. Tetrahedron Letters, 42(37), 6503-6505. doi:10.1016/s0040-4039(01)01222-9

Cobb, A. J. A., Longbottom, D. A., Shaw, D. M., & Ley, S. V. (2004). 5-Pyrrolidin-2-yltetrazole as an asymmetric organocatalyst for the addition of ketones to nitro-olefins. Chemical Communications, (16), 1808. doi:10.1039/b409646k

Flack, H. D. (1983). On enantiomorph-polarity estimation. Acta Crystallographica Section A Foundations of Crystallography, 39(6), 876-881. doi:10.1107/s0108767383001762

Flores, M. F., Núñez, M. G., Moro, R. F., Garrido, N. M., Marcos, I. S., Iglesias, E. F., … Díez, D. (2010). Synthesis of a New Chiral Pyrrolidine. Molecules, 15(3), 1501-1512. doi:10.3390/molecules15031501

MacMillan, D. W. C. (2008). The advent and development of organocatalysis. Nature, 455(7211), 304-308. doi:10.1038/nature07367

Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., … Wood, P. A. (2008). Mercury CSD 2.0– new features for the visualization and investigation of crystal structures. Journal of Applied Crystallography, 41(2), 466-470. doi:10.1107/s0021889807067908

Sheldrick, G. M. (2007). A short history ofSHELX. Acta Crystallographica Section A Foundations of Crystallography, 64(1), 112-122. doi:10.1107/s0108767307043930

Tanaka, F., Mase, N., & Barbas, C. F. (2004). Design and Use of Fluorogenic Aldehydes for Monitoring the Progress of Aldehyde Transformations. Journal of the American Chemical Society, 126(12), 3692-3693. doi:10.1021/ja049641a

Wang, W., Wang, J., & Li, H. (2005). Direct, Highly Enantioselective Pyrrolidine Sulfonamide Catalyzed Michael Addition of Aldehydes to Nitrostyrenes. Angewandte Chemie International Edition, 44(9), 1369-1371. doi:10.1002/anie.200461959

[-]

This item appears in the following Collection(s)

Show full item record