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Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions

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Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions

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Merino Marcos, E.; Poli, E.; Díaz Morales, UM.; Brunel, D. (2012). Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions. DALTON TRANSACTIONS. 41(36):10913-10918. doi:10.1039/c2dt31540h

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/31696

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Title: Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] This manuscript describes the synthesis and structural study of new second generation Hoveyda¿Grubbs catalysts: 1,3-dimesitylacenaphthylenyl- 4,5-imidazolin-2-ylidene (BIAN-NHC) ruthenium isopropoxybenzylidene dichloride ...[+]
Subjects: Face donor properties , Olefin metathesis , Imidazolin-2-Ylidene ligands , Imidazol-2-Ylidene ligands , Cross-metathesis , Catalysts , Metal , Efficient , Bearing , Rcm
Copyrigths: Cerrado
Source:
DALTON TRANSACTIONS. (issn: 1477-9226 ) (eissn: 1477-9234 )
DOI: 10.1039/c2dt31540h
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/c2dt31540h
Thanks:
We thank Dr Berta Gomez-Lor for allowing us to use the cyclic voltammetry instrumentation, Dr J. A. Vidal-Moya for his support in the kinetic experiments and Dr Marcelo Domine for the HRMS measurements. We thank Avelino ...[+]
Type: Artículo

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